氨法烟气脱硫装置气溶胶排放特性研究.docxVIP

-56．第十七届二氧化硫、氮氧化物、汞污染防治技术暨细颗粒物(PM2．5)控制与监测技术研讨会论文集氨法烟气脱硫装置气溶胶排放特性研究 -56．第十七届二氧化硫、氮氧化物、汞污染防治技术暨细颗粒物(PM2．5)控制与监测技术研讨会论文集 氨法烟气脱硫装置气溶胶排放特性研究 杨林军t张文武，沙志强-朱忠益-鲍静静l (1、东南大学能源热转换及其过程测控教育部重点实验室，南京，210096) 2、中石化资产管理公司扬子石化资产分公司，南京，210048) 摘要：结合扬子热电厂II期玛苏莱氨法脱硫工艺运行参数，试验考察了氨法烟气脱硫工艺的气溶胶 排放特性。结果表明：氨法烟气脱硫过程中会产生大量气溶胶颗粒，从数浓度角度而言，主要属亚微 米级微粒，但依据质量浓度分布，呈双峰分布，以微米级及大于l o(m的颗粒物为主：同时，脱硫前后 颗粒物物性发生显著变化，脱硫净烟气中颗粒多呈规则的晶体结构，含长方体、棱柱体等晶习，s、0 元素含量显著增加，主要物相成分为mH。)：s04；最后，对扬子热电厂II期氨法脱硫装置气溶胶颗粒的 来源进行了分析。 关键字：氨法烟气脱硫；气溶胶；排放特性；形成 Aer吣ok Emi鹳ion Chancteri蚰髓du咖卫AmmOnia-bas甜Wn Fhe G雌D鲫Il如ri臻60n Y抽g I．in-junl，Zhang We岫-岬nl 1， Sha 功№ian91，助u功on学刚1，Bao J虹列in91 (1、Key L曩bontory of Ener醑Themal Co删e聃ion叠nd Contml of M铀istry of Edu∞戗on，Schom of Ener醪and En“mnm明t，Sou伍e嬲t Un押e琏i锄Nanj洫g，2100％， China 2、S洒op∞Yan函Petmch哪i姐I C伽pany L坩，N矗nj妯g，21∞46，Chi船) Ah山噜ct：The emission characteristics of aerosol were inVestigated experimentaliy during锄monia-baSed wet flue g越de蛐I如rization(WESP)process according to the practical operation condition of M甜鲫Icx 锄monia-baSed desulmrization process of Y锄gzi themlal power pl卸t．The扯rosol panicles size diStribution 锄d concen仃ation，morphoIogies卸d compositions before卸d aRer de蛐l如rization were measured using Electrical Low PresSure Impactor，Sc锄ning Electron Microscopy锄d XRD，respectiVely．111e rcsultS show that Ia唱er number of aerosol panicles c卸be fonned during the ammonia-based desuImrization process， which c卸sed the morphologies of panicIes in t11e outlet flue gaS of deSul如rization tower vary much．These panicles had the smooth surface and regular cD，stal stmcture，including cuboid and prismoid crystal habits． Before desuI如rization the panicles primariIy silica-alumina mineraIs including o，Al锄d Si，while after desulfurization the main elements S，O and N．The main phase composition of the generated aerosol particIes is ammonium suIfatc Moreover，these aerosof panicles most in the submicron scale for the number concentration． HoweVer th