几种生物分子在化学修饰电极上的电化学行为研究-分析化学专业论文.docxVIP

硕士学位论文 硕士学位论文 ABSTRACT ABSTRACT The chemical modification renders the electrodes special chemical and electrochemical properties．Based on other researchers’work,we hadve developed a series of biological and chemical sensors and investigated the electrochemical behaviors of several biomolecules． establishing the basis for further designing new chemical and biological SenS0rS． 1he SWNT modified electrode was prepared by casting the suspension of SWNls iIl DⅣ匝onto the substrate electrode．The resultant electrode had an extraordinary electrocatalytic activity taward the oxidation of TPHC．In comparison with other kinds of electrode。the sensitivity for determination of TPHC has been greatly improved at the SⅥ仆兀：modified electrode．The involved electrode reaction mechanism has been elucidated in detail．The present method could be used to the determination ofTPHC in real samples with satisfactory results． Voltammetric investigation of surface—confined rabbit liver MT at Nation．coated mercury film electrode(NCMFE)was performed to elucidate the possible redox-modulated metal-transfer processes．Two pairs of well—defined redox peaks were observed for the first time．The NCMFE provides a fast and hil曲ly sensitive way to explore the redox properties of surface．confmed MT． The NCBFE was used to investigate the redox behavior of and metal release from rabbit liver MT in an acetate buffer．A diffusion．controlled Nerstian redox wave of MT was observed．The NCBFE provides an excellent milieu for voltammetric studies of different types of MT and related isoforms，paving the way for studying the redox—modulated metal transfer of MT,and understanding the biological role of MTs in heavy metal detoxification and essential metal regulations． KEY WORDS：Chemical modified electrode，Voltammetry, Triprolidine hydrochloride，Metallothionein Il 原创性声明本人声明，所呈交的学位论文是本人在导师指导下进行的研究 原创性声明 本人声明，所呈交的学位论文是本人在导师指导下进行的