双极膜电渗析法分离发酵液中乳酸及离子迁移规律.docxVIP

第 65 卷 第 12 期 化 工 学 报 Vol.65 No.12 2014 年 12 月 CIESC Journal December 2014 双极膜电渗析法分离发酵液中乳酸及离子迁移规律 林晗 1，汪群慧 1,2，王丽娟 3，李岩 1，陈焕玺 1 （1 北京科技大学土木与环境工程学院，北京 100083；2 工业典型污染物资源化处理北京市重点实验室，北京 100083； 3 山西省环境科学研究院，山西 太原 030027） 摘要：考察了双极膜电渗析法分离酒糟发酵液中乳酸的影响因素，结果表明：当进料浓度 13.5 g·L?1，工作电压 27 V，进料浓度比 1.3，流量 20 L·h?1，电渗析 10 h，产品罐中的乳酸浓度增加至 20.95 g·L?1，是电渗析前进料 罐中的乳酸浓度的 1.6 倍，具有显著的浓缩效果。酸根离子迁移规律的研究表明，乳酸根离子的迁移速率明显高 于其他酸根离子，且丙酸和乙酸的乳酸分离率相对较低。 关键词：发酵；动力学；离子迁移；电渗析；乳酸；分离 DOI：10.3969/j.issn.0438-1157.2014.12.024 中图分类号：X 92 文献标志码：A 文章编号：0438—1157（2014）12—4823—08 Lactic acid recovery from fermentation by bipolar membrane electrodialysis and ionic migration LIN Han1, WANG Qunhui1,2, WANG Lijuan3, LI Yan1, CHEN Huanxi1 (1Department of Environmental Engineering, School of Civil and Environmental Engineering, University of Science and Technology, Beijing 100083, China; 2Beijing Key Laboratory on Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China; 3Shanxi Academy of Environmental Science, Taiyuan 030027, Shanxi, China) Abstract: A series of factors were examined in the separation of lactic acid (HLa) from lees fermentation by bipolar membrane electrodialysis. When the fermentation with the initial HLa concentration of 13.5 g·L?1 was treated by bipolar membrane electrodialysis under the conditions of voltage 27 V, feeding concentration ratio 1.3, and flow rate 20 L·h?1 for 10 h, HLa concentration of discharging tank was 20.95 g·L?1, which was 1.6 times the initial concentration, a significant concentrated effect. Moreover, the analysis of acid ion migration shows that immigration rate of lactic acid ions is significantly higher than that of other acid ions. The relative separation efficiency of HLa to propionate and acetic acid are lower. Key words: fermentation; kinetics; ion mobility; electrodialysis; lactic acid; separation 引 言 乳酸作为一种重要的工业原料，被广泛应用于 食品、医药、日化等行业。尤其是近年来，具有良 好生物相容性和生物降解性的聚乳酸作为骨折内固 件等被应用于医疗行业，进一步激发了乳酸的市场 需求。乳酸主要通过生物发酵法[1-4]和化学合成法生 产[5]。我国是酿酒大国，每年的酒糟产量达千万