以丙烯酸为功能性单体的苯丙乳液聚合及其性能研究.docxVIP

V譬52N V譬52N 。。，悯av5悯ay 2015 Journal of Silk缛润僻翻习 2015年5嚣鬻翥年舄“橐5函 ■霹蠢朦 DOI：doi．org／10．3969／j．issn．1001-7003．2015．05．003 以丙烯酸为功能性单体的苯丙乳液聚合 及其性能研究 徐丽丽，刘增伟，马凤国 (青岛科技大学a．高分子科学与工程学院．b．橡塑材料与工程教育部重点实验室，山东青岛266042) 摘要：以苯乙烯与丙烯酸丁酯为共聚单体，丙烯酸为功能性单体，通过半连续种子乳液聚合制备稳定 的苯丙乳液。研究表明：当NaHCO，质量配比在o．19％～0．3％时，乳液稳定性好；当丙烯酸质量配 比小于2．0时，乳液粒径分布窄，平均粒径为0．18岬，乳液流动性较好，高于2．5时，乳液粒径变大 且分布变宽，乳液呈膏状、流动性差；当丙烯酸质量配比增大时，乳液黏度呈逐渐上升趋势；随着氨水 质量配比的增加，乳液黏度逐渐增大，但达到一定量后保持不变；随剪切速率增大，乳液呈明显的剪 切变稀趋势，说明乳液为假塑性流体。 关键词：苯丙乳液；剪切速率；黏度；粒径 中图分类号：TS959．9；TQ317．4 文献标志码：A 文章编号：1001W003(2015)05—0011-05 引用页码：051103 Study on Styrene．Acrylic Emulsion Polymerization and Its Performance with Acrylic Acid as Functional Monomer XU Lili，LIU Zengwei，MA Fengguo (a．Polymer Science and Engineering；b．Key Laboratory of Rubber—Plastics(QUST)，Qingdao University of Science＆Technology， Qingdao 266042，China) Abstract：Stable styrene—acrylic emulsion is prepared through．semi—continuous seeded emulsion polymerization with styrene and butyl acrylate eomonomer．The research shows that the emulsion has good stability when the mass ratio of NaHC03 is between 0．19％and 0．3％；when the mass ratio of acrylic acid is less than 2．0，the size distribution of emulsion is narrow，the average particle size is 0．18肚m and the emulsion has good liquidity；when it is higher than 2．5，its particle size increases，the size distribution widens and the emulsion has cream shape and poor liquidity；when the mass ratio of acrylic acid increases，emulsion viscosity shows rising trend；with the increase of ammonia water mass ratio，emulsion viscosity increases gradually and remains unchanged after reaching certain value；with the increase of sheafing rate，the emulsion shows an obvious shear thinning trend，showing that the emulsion is pseudoplastic fluid． Key words：styrene—acrylic emulsion；shearing rate；viscosity；particle size 因社会环境安全需求，具有无毒、无味、污染 用限111。近年来关于苯丙乳液合成方法及其性能的 等优点的水溶性乳液逐渐占领市场Ⅲ3，而苯丙乳 研究越来越多，稳定性是评判乳液质量的首要条件， 有较好的耐水性、耐候性、耐碱性等优点，且价格 而通过测量粒径大