加氢润滑油基础油光稳定剂的研制-油气田开发工程专业论文.docxVIP

中史{1j：j篮论文题目：加氢润滑油基础油光稳定剂的研制 中史{1j：j篮 论文题目：加氢润滑油基础油光稳定剂的研制 专业：油气田开发工程 硕士生：张科良 瘩种童 指导教师：徐家业彳兰‘嚣垃 摘 要 加氢润滑油基础油，具有粘度指数高，挥发性低，色度低，折光指数小，对添加剂感受性好， 热安定性好等特点。但同时存在光安定性差的缺点，影响了加氧润滑油基础油的应用和推 广。作者在参考有关文献的基础上，针对加氢润滑油基础油光安定性差的原因，依据加氢润 滑油基础油光氧化的机理，研制出一种高效无灰复合型加氢润滑油基础油光稳定剂，从而 比较好的解决了加氢润滑油基础油光安定性差的问题。 这种高效无灰复合型加氢润滑油基础油光稳定剂由三个组分组成：其一是受阻胺型 光稳定剂；第二个组分是抗氧剂；第三个组分是辅助型光稳定剂一紫外辐射吸收剂。其中 的一种紫外辐射吸收剂为新化合物，目前未见报道。应用红外光谱分析仪，紫外光谱分析 仪，元素分析仪对其进行了结构表征。所有紫外辐射吸收剂的紫外一可见光谱，都进行了测 试。 作者首次应用正交试验设计的方法，对受阻胺型光稳定剂、抗氖剂、紫外辐射吸收剂 之间的相互关系进行了研究。结果表明，癸二酸双(四甲基哌啶醇)酯受阻胺型光稳定剂与 受阻酚类抗氧剂之间存在协同作用，受阻胺型光稳定剂与紫外线吸收剂之问也存在协同 作用。 评价结果表明：添加作者研制的高效无灰复合型光稳定剂0．15％可使兰州炼油化工 。e2,厂生产的125N加氢润滑油基础油保持良好的光稳定性。基础油的透光率、色度优于 添加O，2％目前最好的有机镍盐配合物。 本研究具有一定的理论意义和实用价值。 关键词：加氢润滑油基础油 受阻胺光稳定剂 紫外线吸收剂抗氧剂 光安定性协 同效应 论文类型：应用研究 (自选课题) pⅡ交_i油人学硕十学位沦叟Subject：Study pⅡ交_i油人学硕十学位沦叟 Subject：Study on light stabilizer for Hydrotreated lubricating oils Speciality： Name：Zhang k linstructor：XU Abstract In general，lubricating oils produced by hyarotreating method affords a relatively high viscosity index，lower volatility,lower colority and lower refraction light index，good to additive and good temperature stabilization．However,it is poor stability against ultra—violet light degradation．So its application and popularization were limited． Being aimed at the reason of poor stability against ultra—violet light degradation，according to the oxidation mechanism，one kind of high efficiency ashless light stabilizer was preparated， that was a dustless complex light stabilizer, This kind of high ashlcss efficiency light stabilizer were consisted of three components The first is Hindered Amine Light Stabilizer；the second is an Antioxidant；the third is an assistant light stabilizer—Ultra—violet absorber．Among them．ore kind of ultra—violet absorber is a new compound．[ts structure were characterized by Element analysis，IR analysis and ultra—violet spectrum analysis．The UV-visible absorption of those ultra—violet absorber were also tested． The relation among Hindered Amine Light Stabilize