三溴偶氮胂直接光度法测定铝合金中铈组稀土元素.PDF

Direct Spectrophotometric Determination of Cerium Subgroup of Rare Earth Elements in Aluminium Alloys w ith T ribromoarsenazo ( ) ( ) Wu Ya in ( China Xingping Aircraft Wheel Corporation) Pan T ang Li Li ( Institute of Aeronautical M aterials, Beijing) [ ] ( T BA ) , T BA , 635nm , T BA 1 3, ( 1. 15 5 - 1 - 1 1. 2 5) 10 L mol cm , ( 025) g/ 50m L , [ Abstract ] In this paper , the colour reaction of the cerium subgroup of rare earth elements ( ) . w ith tribromoarsenazo TBA has been studied Cerium subgroup reacts with the reagent in strong acid medium of HCl to form a blue violet complex w hich has a maximum absorption at 635nm and its molar ratio of Ce subgroup to TBA is 1 3. The apparent molar absorptivity is ( 1. 15 5 - 1 - 1 1. 25) 10 L mol cm . Beer s law is obeyed in ( 02 5) g/ 50mL. T he method has been ap- plied to the direct photometric determination of the Ce subgroup in aluminium alloys w ith satis- factory results . Keywords tribromoarsenazo cerium subgroup of rare earth elementsaluminium alloys , , , 1 , [ 1] 1. 1 PMBP - , , , PM BP , 72 1 ( ) , 1+ 1; 50 g/ L ; 30% HB 5218 [ 2- ( 2- ) - 7- ( 2 , 20, , 4, 6- ) - 1, 8- - 3, 6 - , , TBA ] 0. 5g / L 0. 20 / 0. 12 28 ( ) ,