坡缕石黏土污泥对水相中亚甲基蓝吸附研究-中国环境科学.PDF

中国环境科学 2014,34(1) ：78~84 China Environmental Science 坡缕石黏土污泥对水相中亚甲基蓝吸附研究 高淑玲,杨翠玲,罗鑫圣,周鹏鑫,张 哲* (西北师范大学化学化工学院,甘肃省高分子材料重点实验室,生态环境 相关高分子材料教育部重点实验室,甘肃 兰州 730070) 摘要：利用坡缕石黏土污泥(从木质素磺酸钠废水中得到)和酸化的坡缕石黏土(1mol/L 盐酸)作为吸附剂对水相中的亚甲基蓝进行吸附研 究,并利用透射电镜(TEM)、红外光谱(FT-IR) 、X-射线衍射(XRD)及 Zeta 电位分析对两种吸附剂的结构及表面电性进行了表征.结果表明: 当吸附剂用量为 10mg,温度为 30℃时,1mol/L 盐酸酸化的坡缕石黏土最大吸附量为 97.50mg/g,坡缕石黏土污泥最大吸附量为 98.7mg/g.选 取坡缕石黏土污泥作为最佳吸附剂,对污泥吸附亚甲基蓝的吸附等温线、吸附热力学及吸附动力学模型进行了研究,结果显示:此吸附过程 为自发吸热过程,吸附等温线更符合 Langmuir 模型,吸附动力学符合准二级动力学模型. 关键词：坡缕石黏土污泥；亚甲基蓝；吸附热力学；动力学；吸附模型 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2014)01-0078-07 Study on methylene-blue adsorption from water phase by palygorskite clay sludge. GAO Shu-ling, YANG Cui-ling, * LUO Xin-sheng, ZHOU Peng-xin, ZHANG Zhe (Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, China). China Environmental Science, 2014,34(1)：78~84 Abstract ：The absorption effect of the palygorskite clay sludge (obtained from the sodium lignosulfonate wastewater) and acid-treated palygorskite (1mol/L HCL) was investigated, methylene blue in aqueous solution as an adsorbate. The structure and surface electricity-performance of two types of adsorbents were characterized by transmission electron microscopy (TEM), FT-IR spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XRD) and zeta potential. The results showed that the maximum adsorption capacities of palygorskite clay sludge and acid-treated palygorskite were 98.7mg/g and 97.50mg/g at 30℃, respectively. When the palygorskite clay sludge was selected as the adsorbent, the