环氧树脂固化行为的动力学分析 毕业论文.docVIP

PAGE PAGE II Kinetic Analysis of Epoxy Resin Curing 环氧树脂固化行为的动力学分析 摘要 本文主要介绍了环氧树脂和固化剂等的相关知识以及国内外的研究进展情况。本实验以4,4-二甲氧甲基联苯为单体，合成了一种新型含联苯结构的环氧树脂，并与酚醛胺（T-31型）环氧固化剂发生固化反应，对环氧树脂的固化性能进行了研究。利用VETOR33傅立叶变换红外光谱仪(FTIR)以及XD-3型多晶X射线粉末衍射仪（XRD）对反应得到的环氧树脂和固化产物的分子结构以及其晶态结构进行表征，从而得到表观固化反应的定量结果。结果表明:联苯酚醛环氧树脂与T-31型固化剂反应的产物的最佳固化时间为常温12小时+60℃2小时。 关键词：联苯，环氧树脂，固化反应，表征 Kinetic Analysis of Epoxy Resin Curing ABSTRACT This article mainly introduced the epoxy resin，the curing agent and so on related knowledge and the domestic and foreign newest research development. A new type of epoxy resin containing biphenyl was synthesized with 4,4 - dimethoxy methyl biphenyl monomer. And phenolic amines epoxy curing agent T-31 was used as a curing agent of epoxy resin to study the curing properties.With VETOR33 fourier transform infrared spectroscopy (FTIR) and XD-3 type polycrystalline X-ray powder diffraction (XRD) , the reaction of the polymers structure and its crystal structure can be characterized.Then we can see the quantitative results by apparent cure reaction . The results showed that: the optimum curing time of biphenyl phenolic resin and T-31 curing agent reaction was 12 hours at room temperature adds 2 hours at 60 degrees. KEYWORDS：biphenyl，epoxy resin，curing reaction，characterization 目录 摘要(中文) …………………………………………………………………………………Ⅰ 摘要(外文)…………………………………………………………………………………Ⅱ 1 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc263416871 文献综述 PAGEREF _Toc263416871 \h 2 HYPERLINK \l _Toc263416872 1.1环氧树脂 PAGEREF _Toc263416872 \h 2 HYPERLINK \l _Toc263416873 1.2环氧树脂的分类 PAGEREF _Toc263416873 \h 2 HYPERLINK \l _Toc263416874 1.3液晶环氧树脂 PAGEREF _Toc263416874 \h 3 HYPERLINK \l _Toc263416875 1.4固化剂 PAGEREF _Toc263416875 \h 4 HYPERLINK \l _Toc263416876 1.5固化机理 PAGEREF _Toc263416876 \h 4 HYPERLINK \l _Toc263416877 1.6国外研究现状 PAGEREF _Toc263416877 \h 4 HYPERLINK \l _Toc263416878 1.7国内研究状况 PAGEREF _Toc263416878 \h 6 HYPERLINK \l _Toc263416879 1.8 研究目的和意义 PAGEREF _Toc263416879 \h 9 HYPERLINK \l _Toc2