溶胶凝胶毛细管气相色谱柱测定指甲油中邻苯二甲酸酯.PDFVIP

9 4 () Vo.l 9 No. 4 2009 12 JOURNAL OF NAN JING NORMAL UN IVERSITY ( ENG INEERING AND TECHNOLOGY EDIT ION ) De , 2009 溶胶凝胶毛细管气相色谱柱测定 指甲油中的邻苯二甲酸酯 王东新 ( , 210097) [ ] 5 () : ( DM P) ( DEP)(DBP)( 2) ( DEH P)( DOP). , , . 6 5 . : 016 ~ 050 ng; 954% ~ 1004% ; 117% ~ 291% . [ ] , , [ ] O 675. 8 [ ] A [] 2009) Determination of the Amount of Phthalates in Nail Polishes on a SolGelGas Chromatographic Capillary Column W ang Dongx in ( S hool of Ch em istry and Environm ental S ien e, Nanjing N orm alUn iversity, N anjing 210097, Ch ina) Abstract: The am ount of 5 phthalates in nail polishes in lud ing DM P, DEP, DBP, DEH P and DOP w erem easured by apillary gas hrom atography. The dried nail polishesw ere d issolved in a etonew ith u ltrasoni ation. The hrom atograph i analys is w as arried out on a solgel ap illary olumn wh i h show ed high stab ility and ex ellent separation. Inner standard m ethod w as app lied in quantitative analysis. The dete tion lmi its w ere 016 050 ng. The re overies for ph thalates were 954% 1004% . The relative standard deviations for the am ount of phthalates in nail polishes were 117% 29 1% . K ey words: solgel gas hrom atograph i apillary olumn, phthalate, nail polish () . , ; ; . , . . , . , [ 1, 2] . . . , . 1 实验部分 11 FID 4890D (); KQ 218( ); WH2( ); 800( ); ; 053 mm i. d. (); : : ,, , : . Em ail: w angdongx in@ njnu. edu. n 53 () 9 4( 2009) ( PDM S)( PMHS) (); ( AR, ); (AR, () ); ( ); ( DM P) (AR