硅酸钠溶液合成托贝莫来石晶须-硅酸盐学报.PDF

40 12 α/β Si N 1721 3 4 40 12 Vol. 40 No. 12 2 0 1 2 1 2 JOURNAL OF THE CHINESE CERAMIC SOCIETY December 2012 ( 410000) 5 1.1 nm 5 213 μm0.20.5 μm210 μm0.21.0 μm 1.1 nm TB3221 X751 0454–5648(2012)12–1721–07 2012–11–29 10:09:55 /kcms/detail/11.2310.TQ1009.201212.1721_012.html Preparation of Tobermorite Whisker from Sodium Silicate Solution LI Guanghui ZHANG JiqingLUO Jun CHEN HaoyuanZENG JinghuaJIANG Tao (School of Minerals Processing Bioengineering, Central South University, Changsha 410000, China) Abstract: Tobermorite was synthesized with sodium silicate solution as silicous material by dynamic hydrothermal synthesis method. The effect of synthesis conditions on the purity and morphology of tobermorite was investigated. The main phase of the product syn- thesized from sodium silicate and lime milk was pectolite. In the presence of caustic soda, pectolite was converted partly into clinoto- bermorite. And the amount of clinotobermorite increased with the increasing of caustic soda concentration. Pure 1.1 nm tobermorite was obtained when aluminum ion was added at a calcium/aluminum mole ratio of 5. The growth of tobermorite whisker was en- hanced by the presence of chlorine ion in the solution. At a calcium/chlorine molar ratio of 5, the tobermorite whiskers obtained were 2–13 μm in length and 0.2–0.5 μm in diameter. With a practical sodium silicate solution containing alkali and aluminum as the mate- rial, tobermorite whiskers with 2–1