铝土矿中含钛矿物在矿浆预热过程中反应动力学研究-矿冶工程.PDF

25 4 矿　冶　工　程 Vol.25 №4 200508 MINING AND M TALLURGICAL NGIN RING August 2005 1, 2 1 2 尹中林 , 毕诗文 , 顾松青 (1. , 110004;2., 450041) 　:, , 。 180～ 260 ℃84.4 kJ mol。 180 ～260 ℃ 。 。 。 , 。 :;;;;;; :TF802.6;TF821 :A :0253-6099(2005)04-0054-04 Study of Reaction Kinetics of Ti-containing Minerals in Preheating Process of Bauxite Slurry 1, 2 1 2 YIN Zhong-Lin , BI Shi-wen , G Song-qing (1.School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;2.Alumina Research Department, ZhengzhouLightMetalResearch Institute, Zhengzhou 450041, enan, China) Abstract:An investigation is made of the reaction kinetics of Ti-containing minerals using diasporic bauxite as raw material according to the principle of the equal-reaction efficiency method.The Ti-containing minerals have an appearant activation enengy of 84.4 kJ mol during the reaction of detitanization in slurry-areheating at 180～260 ℃and the detitanization reaction of Ti-containing minerals is controlled by surface chemical reaction kinetics in the range of 180 ℃to 260 ℃.Themass trans- fer process in ion diffusion is not the keyfactor affecting reaction velocity, and the flow velocity and flow state also have no ob- vious effect on the reaction velocity.The reaction of Ti-containing minerals during high temperature preheating accelerateswith the rise of tempevature, resulting in speeding up of scaling of Ti-containing minerals during high temperature preheating. Key words:diasporic bauxite;preheating process;Ti-containing mineral;detitanium reaction;reaction kinetics;apparent activation energy;scaling process 　　 CaO MgO 。2%～4%TiO2,