聚乳酸滑石粉结晶动力学的研究毕业论文.doc

聚乳酸滑石粉结晶动力学的研究毕业论文 PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT III 聚乳酸/滑石粉结晶动力学的研究 摘要：采用密炼机熔融混炼制备了聚乳酸（PLA）基生物降解材料，并以滑石粉（Talc）作为成核剂，聚乙二醇(PEG)为增塑剂，研究了它们单独以及共同对PLA结晶能力的影响。使用DSC和热台偏光显微镜研究了PLA/Talc、PLA/PEG和PLA/PEG/Talc共混体系的等温结晶动力学，对所得数据用Avrami方程进行了处理，并计算了其活化能，结果表明：随着Talc的不断加入，加快了成核速率和球晶生长速率，缩短了半结晶时间并降低了活化能，表明Talc是有效的成核剂。而PEG的不断加入，提高了其结晶温度区间，并且球晶尺寸变得更大、更加完善，说明PEG是一个很好的增塑剂。 关键词：聚乳酸；增塑剂；成核剂；等温结晶动力学 PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT IV The Study of Crystallization Kinetics of PLA/Talc composites Abstract：The polylactic acid （PLA） based biodegradable materials were prepared by using internal mixer，which took the method of melt-mixing，Talcum powder （Talc） as nucleating agent and PEG as plasticizer. We were studied the influence of plasticizer and nucleating agent to the crystallization of PLA. The isothermal crystallization kinetics of PLA and its composites with Talc or PEG or both of them was analyzed by DSC and POM. Processing of the Talc obtained using the Avram equation and calculate its activation energy,The results showed that, With the addition of nucleating agent Talc， accelerated the nucleation rate and spherulite growth rate， shorten the half crystallization time and reduces the activation energy，That Talc is an effective nucleating agent. With the addition of plasticizer PEG, improved the crystallization temperature range, and the spherulite size become bigger、 more perfect, shows that PEG is a good plasticizer Key words： polylactic acid; plasticizer；nucleation agent; the isothermal crystallization kinetics PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT V 目 录 TOC \o 1-3 \h \u HYPERLINK \l _Toc13982 摘要 PAGEREF _Toc13982 I HYPERLINK \l _Toc27184 Abstract PAGEREF _Toc27184 II HYPERLINK \l _Toc18700 目 录 PAGEREF _Toc18700 III HYPERLINK \l _Toc7988 1.绪论 PAGEREF _Toc7988 1 HYPERLINK \l _Toc26166 1.1前言 PAGEREF _Toc26166 1 HYPERLINK \l _Toc4016 1.2聚乳酸的合成、性能与应用 PAGEREF _Toc4016 1 HYPERLINK \l _Toc18157 1.3聚乳酸结晶过程的研究方法 PAGEREF _Toc18157 3 HYPER