超支化聚酰亚胺的改性研究3.PDF

第 2 1 卷 第 78 期 化 　学 　进 　展 Vol . 2 1 No . 78 2009 年 8 月 PROGRESS IN CHEMISTRY 　Aug. , 2009 超支化聚酰亚胺的改性研究 陈文求 　杨小进 　李全涛 　易昌凤 　徐祖顺 (湖北大学材料科学与工程学院　武汉 430062) ( ) 摘 　要 　超支化聚酰亚胺 HBPI 因其独特的结构特征 、优异的理化性能和广泛的应用价值而备受关 注 ,其改性研究更是该领域的重点和热点 。本文综述了 HBPI 近年来的改性研究以及最新进展 ,重点介绍了 官能团改性 、与无机纳米粒子杂化改性 、与有机聚合物复合改性 、交联改性以及引入其他特殊结构单元的改 性方法 ,并对其表征和应用进行了相关概述 。 关键词 　超支化聚酰亚胺 　官能团改性 　复合改性 　交联改性 ( ) 中图分类号 : O6335 ; TQ3237 ; TQ3166 　文献标识码 : A 　文章编号 : 1005281X 2009 078156008 Modif ication Research of Hyperbranched Polyimide Chen Wenqiu 　Yang X iaoj in 　L i Quantao 　Yi Changf eng 　X u Zushun (College of Materials Science and Engineering , Hubei University , Wuhan 430062 , China) Abstract 　Hyperbranched polyimide ( HBPI) has attracted much attention due to its unique structural characters , excellent physical and chemical properties as well as its widely applied values. And its modification research is the emphases and hotspot in this field . The modification research and recent development of HBPI are reviewed in this paper . Functional group modification , inorganic nanohybrid modification , organic polymer compound modification , crosslinking modification and some other methods like introducing special structure group s , are emphatically introduced . Characterization and application of HBPI are also summarized . Key words 　hyperbranched polyimide