杜氏盐藻热解动力学研究.docVIP

PAGE 1 杜氏盐藻热解动力学研究 邹树平1, 2吴玉龙1 杨明德1﹡张建安1 童军茂2 （1. 清华大学核能与新能源技术研究院 北京 102201；2. 石河子大学食品学院 石河子 832000） 摘　要: 本文通过热重分析手段研究了杜氏盐藻在室温至900℃下的热解行为和特性，采用高纯氮气做保护气，升温速率分别为5、10、20和40°C·min-1。TG、DTG曲线的分析表明热解过程随温度升高经历三个不同阶段。此外，随着升温速率增大，热解的初始温度和峰值温度均增大，且总失重量明显增加。采用等转化速率法和主曲线法对盐藻热解过程进行动力学分析。结果表明，表观热解反应遵循单一动力学机理模型，反应动力学过程为简单级数反应机理模型，并求得了热解反应表观平均活化能和指前因子，所得盐藻热解动力学方程为： 关键词: 微藻；热重分析；等转化速率法；主曲线法 中图分类号：TK6 文献标志码：A 文章编号: STUDY ON THE DYNAMICS OF PYROLYSIS PROCESS DUNALIELLA TERTIOLECTA ZOU Shu-ping1,2 WU Yu-long1 YANG Ming-de1 ZHANG Jian-an1 TONG Jun-mao2 (1. Institute of Nuclear and New Energy Technology, Tsinghua university, Beijing 102201, China； 2. Food College, ShiHeZi University, ShiHeZi 832000, China) Abstract: In this paper, the pyrolysis characteristics of Dunaliella tertiolecta was investigated by the thermogravimetric analysis. The experiments are carried out with a thermogravimetrc analyzer from ambient temperature to 900℃ at different heating rates of 5, 10, 20, 30 and 40 °C·min-1 under high purify N2. TG and DTG analysis are adopted to study the pyrolysis behavior of Dunaliella tertiolecta systematically. Results showed that three stages appeared in the pyrolysis process with increasing temperature. Moreover, the initial temperature of pyrolysis and the temperature at which the pyrolysis rate reaches the peak value rose with the heating rate increasing. The kinetic analysis was performed by using a composite procedure involving the iso-conversional method and the master plots method. The iso-conversional method indicated that the pyrolysis reaction can be dealt with as single reaction model, and the master plots method reveals this process conforms to simple order reaction mode. The kinetic parameters, such as activation energy and pre-exponential factor, were calculated, respectively. Acoordingly kinetic equation can be deduced as: Keyword: Dunaliella tertiolecta; thermogravimetric; iso-conversional method; master plots method 引