制冷用凹土.pdf

第23 卷第2 期 高 校 化 学 工 程 学 报 No.2 Vol.23 2009 年 4 月 Journal of Chemical Engineering of Chinese Universities Apr. 2009 文章编号：1003-9015(2009)02-0290-07 制冷用凹土-氯化钙复合吸附剂的制备和吸水性能 陈海军, 崔 群, 陈修军, 唐 颖, 姚虎卿 (南京工业大学 化学化工学院, 江苏 南京 210009) 摘 要：制备了凹土-氯化钙复合吸附剂，通过静态称重法测定了其吸水性能。考察了制备方法、焙烧温度和时间以及 原料比例等制备工艺条件对复合吸附剂性能的影响，优化了制备工艺。采用 X 射线衍射和低温氮吸附对复合吸附剂进 行了表征。结果表明：焙烧温度对复合吸附剂吸水性能影响较大，较佳的制备工艺条件是采用溶解-混合法、焙烧温度 300℃、焙烧时间 2 h 。低相对湿度时(20%)吸附剂吸水受微孔和氯化钙含量共同作用，高相对湿度(30%)时吸水性能 主要和氯化钙含量有关。20 ％氯化钙含量的凹土吸附剂，在相对湿度为20 ％，吸水量为0.30 kg⋅kg− 1 ；相对湿度 80 ％， 吸水量超过 0.65 kg⋅kg− 1 ；该吸附剂可反复再生。 关键词：复合吸附剂；吸附；制冷；凹土；氯化钙 中图分类号： TQ 424.29 文献标识码： A Preparation and Water Adsorption Performance of Attapulgite Based Calcium Chloride Composite Adsorbents for Cooling and Air Conditioning Applications CHEN Hai-jun, CUI Qun, CHEN Xiu-jun, TANG Ying, YAO Hu-qing (College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract: A series of attapulgite based CaCl composite adsorbents (AT-CaCl ) were prepared, and their water 2 2 adsorption performances were determined through static weighting method. The effects of preparation method, calcination temperature and time and calcium chloride content on the water adsorption performance of the prepared AT-CaCl2 were investigated, and the preparation conditions were optimized. The prepared composite adsorbents were characterized by X-ray diffraction and low temperature N2 adsorption. The results show that, among the preparation conditions, the calcination temperatu