中子辐照对6H.pdfVIP

第37 卷第4 期 曾晓辉等：水泥水化放热与电阻率变化 · 605 · 第37 卷第4 期 硅 酸 盐 学 报 Vol. 37 ，No. 4 2 0 0 9 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2009 中子辐照对6H-SiC 晶体比热容的影响 马鹏飞，阮永丰，洪晓峰，张守超，贾 敏，张宇晖 (天津大学理学院，天津 300072) 摘 要：用剂量为8.2 × 1018/cm2 的中子对6H-SiC 晶体进行了辐照。采用X 射线衍射仪、差示扫描量热仪测试6H-SiC 晶体中辐照损伤。结果表明： 中子辐照对6H-SiC 样品产生了严重损伤，且辐照后的6H-SiC 的比热容明显上升。对辐照样品进行了常温至1200 ℃的退火处理，退火后的辐照样品 的比热容先随退火温度的升高而逐渐降低，1 000 ℃时比热容到达最低值；当退火温度超过1 000 ℃时晶体的比热容反而上升。运用从头算方法定性计 算了晶体中间隙原子对比热容的影响。结果表明：晶体经中子辐照及退火后，其比热容发生变化的主要原因在于晶体中间隙原子的浓度的变化。辐照 后的样品在超过1 000 ℃退火时比热容的反常回升现象，极有可能与辐照前对晶体所作的在1 000 ℃的预退火处理有关。 关键词：碳化硅晶体；中子辐照；比热容 中图分类号：O77+4 文献标志码：A 文章编号：0454–5648(2009)04–0605–04 EFFECT OF NEUTRON-IRRADIATION ON SPECIFIC HEAT CAPACITY OF 6H-SiC CRYSTAL MA Pengfei ，RUAN Yongfeng ，HONG Xiaofeng ，ZHANG Shoucha ，JIA Min ，ZHANG Yuhui (School of Science, Tianjin University, Tianjin 300072, China) Abstract: 6H-SiC single crystals were neutron-irradiated up to a dose of 8.2 18 2 × 10 /cm . The radiation damages in the single crystals were investigated by means of X-ray diffraction, differential scanning calorimeter and so on. It is found that there are serious damages in the neutron-irradiated 6H-SiC crystals. The specific heat capacity of the neutron-irradiated SiC crystals rises obviously. After an- nealing from the room temperature to 1 200 ℃, the specific heat capacity of the samples reduced with the annealing temperature rising. The influence of interstitial atoms to the specific heat capacity was calculated quantitatively by the ab initio method. The results show that the increase of the specific capacity heat of the neutron-irr