溶胶凝胶化学与工程.pptVIP

Transparent conducting ATO, ITO and AZO coatings by sol-gel process Development of Large Area Electrochromic Display Devices Corrosion Protective Coatings for Al, Mg, Cu, Fe Tarnish and wear protection for stainless steel Strengthening of thin glass by Sol-Gel-Coatings Scratch Resistant Transparent UV-protective Coatings Sol-Gel Coatings for Improved High Temperature Stability of Glass Fabrics Bulk Nanomers for optical applications Micropatterns in Nanomer or glasslike sol-gel films Fabrication of SiO2-based single lenses and arrays of microlenses by ink-jet-printing and pad printing Ceramic UF Membranes Examples of colloid colored bulbs of halide lamps 溶胶凝胶的典型例子 溶胶凝胶（物理过程） 溶胶凝胶（化学过程） Simplified chart of sol-gel processes Sol-gel process Sols Size range for sols Type of sols Types of colloids Gels Gelation Sol-gel process 胶体化学历史 胶体化学历史II 溶胶凝胶技术发展史 溶胶凝胶技术发展史II 国际会议 国内会议 Books Advantages Advantages II Limitations Two other soft-chemical routs Outline Table of content 1. Solvents Water, H2O Results of polar structure I Results of polar structure II Auto-dissociate Non aqueous solvents Classification Amphoteric solvents 2. Precursors transformations Chemical potential of the electrons and electronegativity of an isolated atom Partial charge model Electronegativity scales Allred-Rochow’s electronegativity Water as an example Complex transformation [Co(NH3)6]Cl3 Nucleophilic addition Dissociative mechanism Associative substitution Interchange substitution Bidentate Typical chelating ligands (2; bidentate, 3; tridentate, 4; tetradentate, and 6; hexadentate) 3. Metal Salts Solution Hydrolysis Formation of hydroxo ligands Deprotonation mechanism with hydroxo ligand Formation of hydroxo ligands from oxo ligands The mechanism Formation of oxo ligands Partial charge model (PCM) and hydrolysis PCM and Aquo, oxo domains PCM and the first deprotonation constant K11 Condensation of cations in solutions, polymerization Condensation by olation Nucleophilic addition Associative