浓缩柱富集.pdf

4 4 Vol. 4 No. 4 2013 8 Journal of Food Safety and Quality Aug. , 2013 - * 俞凌云, 董 伟, 温演庆 , 吴孟茹, 金 晶, 胡 毅 (, 610041) 摘 要: 目的 方法 4%, (FIA)(MTB) , 结果 , 2~90 µg/L , , r=0.9991, 1.6%(20 µg/L Pb, n=10), 0.34 µg/L结论 , FIA , 关键词: ; ; ; Spectrophotometric determination of trace lead in food contact materials by concentrated enrichment-flow injection analysis * YU Ling-Yun, DONG Wei, WEN Yan-Qing , WU Meng-Ru, JIN Jing, HU Yi (Inspection and Quarantine Technical Center of Sichuan Entry-Exit Inspection and Quarantine Bureau, Chengdu 610041, China) ABSTRACT: Objective To enrich trace lead in food contact materials by low concentration column. Me- thods Samples were extracted by 4% boiled acetic acid, reacted with methyl thymol blue in FIA. Chelate was de- tected by spectrophotometry. Results The linear range of standard solutions was from 2 µg/L to 90 µg/L (correla- tion coefficient r=0.9991). The relative standard deviation (RSD) was 1.6% (n=10) obtained by injecting standard solution with 50 μg/L lead. The detection limit was 0.34 µg/L. Conclusion This new concentration column is feasible in the enrichment of trace lead from aqueous solutions. It can be used as a fast online analysis method combined with FIA. KEY WORDS: flow injection analysis; lead; enrichment; spectrophotometry 30