铝表面高防护性稀土铈转化膜的研究-材料物理与化学专业毕业论文.docxVIP

IIILLI IIILLI 1 11111 II II II III qlll 摘要 Y1 8 1 2 1 26 摘 要 f‘ 基于目前国内外文献中关于铝合金稀土转化膜研究存在的问题，考虑到铝多 孔阳极氧化膜的优良性能和多孔结构特点，本文采用阴极电沉积和化学沉积两种 方法在铝阳极氧化膜上制各高防护性稀土铈转化膜，系统研究了两种方法成膜的 可能性和膜的耐蚀性，为铝表面稀土转化膜的进一步研究提供基础性依据。 首先，用点滴腐蚀实验确立了在铝阳极氧化膜上形成阴极电沉积铈转化膜j 化学沉积铈转化膜的工艺方法。用正交优化设计获得最佳阴极电沉积和化学沉积 工艺参数，分析了工艺参数对膜的耐蚀性影响。探讨了两种铈转化膜的成膜机理， 比较了两种铈转化膜成膜机理的异同点。最后，用电化学方法如极化曲线法、EIS 交流阻抗法对阴极电沉积铈转化膜、化学沉积铈转化膜进行耐蚀性评估。结果表 明，阴极电沉积铈转化膜或化学沉积铈转化膜的腐蚀电流均比阳极氧化膜的腐蚀 电流小一个数量级，而铝／阳极氧化膜界面电荷传递电阻比阳极氧化膜的大一个数 量级。膜的耐蚀性显著提高的原因在于在阳极氧化膜上形成一层铈转化膜，改变 了阳极氧化膜多孔层形态，氯离子的吸附受到抑制。SEM和EDS对高防护性稀土 铈转化膜形貌和成分分析结果以及经两种方法处理后阳极氧化膜厚度的增加均可 证明铈转化膜高防护性原因的合理性。模拟出铝阳极氧化阴极电沉积或化学沉积 形成铈转化膜体系的等效电路模型。 研究结果表明，在铝阳极氧化膜上经过阴极电沉积或化学沉积可制备稀土铈 转化膜。与铝阳极氧化膜相比，两种铈转化膜的耐蚀性显著提高，且阴极电沉积 稀土铈转化膜的耐蚀性优于化学沉积铈转化膜的耐蚀性。 关键词： 铝阳极氧化阴极电沉积 化学沉积铈转化膜耐蚀性 I ，， ‰ 。 。 H14，ib AbstractAbstract Abstract Abstract On the base of the problems existed in the present references about the studies on rare earth membrane on the surface of aluminum alloy and consideration of the excellent performances of aluminum alloy anodized membrane and its structural porosity characteristic， 80 the rare earth membrane with good protection trait would be formed by the two methods of cathodic electrodeposit and chemical deposit on aluminum anodized membrane．It would be investigated by the numbers that the two kinds of forming film possibilities and the resistance against corrosion of formed film in order to afford the basic evidence for the further study Oil the rare earth conversion membrane on the surface of aluminum in this paper． Firstly,it were established by drop corrosion test that the technical methods for the cerium conversion film formed on aluminum anodized membrane by cathodic eleetrodeposit or chemical deposit．弧eir optimum technical parameters were gained through orthogonal optimization design,the effects that their technical parameters change hM on the corrosion resistance of each cerium conversion film were analyzed respectively．Secondly,each film forming mechanism was diseased，and it W