无锡钢电镀过程中阳极材料电化学特性.pdfVIP

第32 卷第12期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol. 32, No. 12 2 0 1 1 年 12 月 Journal of Northeastern U ni ersity( Natural Science) D ec. 2 0 1 1 付高峰, 李建中, 陶绍虎, 田彦文 ( , 110819) : , . , . , , . , , , , ; . : ; ; ; ; ; : T F 803. 27 : A : 1005-3026( 20 11) 12- 1729-04 Electrochemical Performance of Anodic Materials in TFS Plating Process F U Gao-f eng, LI Jian-z hong, TA O Shao-hu, TIA N Yan-w en ( School of Materials Metallurgy , Nort heastern Uni ersity , Shenyang 110819, China. Corresponding author : LI Jian-zhong, E-mail: lijz @ smm. neu. edu. cn) Abstract: To re eal the electrochemical performance of anode materials in the plating process of T FS products, the electrochemical impedance spectrum ( EIS) of anodic materials in Cr ion solution, F ion solution and the mixture of Cr and F ion solutions w as in estigated ia an electrochemistry w ork station. The results show that the polymerization structures of Cr ion, F ion and the mixture of Cr-F ions on anode surface ha e a remarkable effect on the electrochemical performance of the anode materials. Inducti e reactance phenomenon is obser ed on EIS for C anode and lead alloy anode in Cr ion solution, and their polarization resistance alue are small. Polarization resistance alue of lead ox ide anode is relati ely higher. When F ions are added into Cr ion solution, the inducti e reactance phenomenon of C anode and lead alloy anode surface disappears in the mixture of Cr-F ion solution, while the polarization resistance alue of C anode increases and that of lead ox ide anode decreases. But the polarization resistance alue of lead alloy anode is higher than those of C anode and lead ox ide anode. The conductance of lead ox ide anode is impro ed greatly in th