沉淀分级法调制纺丝级高熔点聚碳硅烷Modulation.pdf

24 1 JOURNAL OF NATIONAL UNIVERSITY OF DEFENSE TECHNOLOGY Vol124 No1 1 2002 : 1001- 2486 ( 2002) 01-0039- 05 X 楚增勇, 刘辉, 冯春祥, 王应德, 薛金根, 宋永才, 邹治春 ( , 410073) : , , ( 280e ) , 10- 30wt% , ( 250e ) : ; ; ; : TQ314 : A Modulation o fSpinnable Polycarbosilane with a High Melting Point via Fractional Precipitation CHU Zeng- yong, LIU Hui, FENG Chun-xiang, WANG Ying- de, XUE Jin- gen, SONG Yong- cai, ZHOU Zh-i chun ( College o fAerospace and Material Engineering, National Univ. o fDefense Technology, Changsha 410073, China) Abstract: As a preceramic polymer to silicon carbide fibers, polycarbosilane ( PCS) should have both a relatively higher melting point ( m1 p1) and a relatively good spinnability1 However, to increase m1 p1 means a rigid requirement for the synthesis conditions1 To solve this problem, we firstly obtain a higher m1 p1 ( 280 e ) PCS fraction via fractional precipitation, and then add 10- 30wt% o fa lower m1p1 fraction to above PCS, thus obtain PCS mixture, then, both have a higher m1p1 ( 250 e ) and a relatively good spinnabi-l ity1 Key words: Polycarbosilane; fractional precipitation; high melting point; spinnability ( Polycarbosilane, PCS) ( Silicon Carbide, SiC) , , PCS 190 e , , SiC ,