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1998 9 EN V IRO N M ENT A L SCIEN CE Sep. , 199 8
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杨 震 乔维川 张晋华 王世明 高松亭 章蕙珠
( , 2 10094 E-m ail y angz @ mail . n just . edu. cn) ( , 2 10093)
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N L G , 430 , 360 ,
87. 5% , 4 1. 3% , 88. 3, 12000 , 205 ,
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The Preliminary Research on the Selection of Catalyst and Mechanism
in Catalytic Degradation of Waste Polyolefins
Y ang Zhen Q iao Weichu anZhang Jinhu aWang Shim ing
( D ept . of Env iron. Sci. an d En g . , N anji ng U niv . of Sci. an d T ech. , N anjing 2 10094 E -m ail y angz @ mail. njus t . edu. cn)
G ao So ng ting Zh ang Hu izhu
( D ept . of En v iron. Sci . and Eng . , N anjing U n iv . , N anjin g 2 10093)
AbstractT he cat alyt ic degr adat io n of w ast e polyol ef ins and reco very of fu el o il w ere st udied
w hen applied variou s cataly st s , t he pyro lysis m echanism of w ast e polyo lef ins w as investig at ed .
T he results show ed t hat , the N LG cat alyst containing big pore zeo lite is w it h a go od cat aly tic
eff ect iv eness . U nder pyroly sis t emperat ure 4 30 , cat alyt ic t em perat ure 360 , w hen N L G w as
u sed, t he product io n rat e o f f uel oil w as 87. 5 % , t he g asoline in w hich w as 41. 3% and t he R O N
w as 88. 3. T he pr odu ct ion co st of t his cat alyst w as only 12, 000 Y uan/ t . Aft er recy cling u sed
and reg enerated f or 205 tim es , it w as st ill w it h a g ood cataly tic ef fect iveness .
, , , .
Keywords w aste poly olefin s pyro lysis zeolit e cat aly st gasoline
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, 70 1. 1
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