镁合金微弧氧化生物医用陶瓷层的结构与性能研究-材料物理与化学专业毕业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - IV - Abstract Ceramic coatings containing Ca and P have been successfully formed on the surface of Mg alloys by Micro-arc oxidation (MAO) in this paper. The composition, chemical structure, surface characterization, frictional behaviors and corrosion resistance were studied by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), friction test and electrochemical measurement systematically. XPS survey spectra indicate that ceramic coatings containing Ca and P have been successfully formed on the surface of Mg alloys by MAO. As treating voltage increases from 400V to 500V, Ca/P first increases and then decreases. There is an optimal voltage (450V) corresponding to the highest ratio of Ca/P. Ca/P increase with the increase of concentration of the solution. AFM results show that the root-mean-square roughness (RMS) of Mg alloys increase remarkably after MAO treated. The RMS of MAO treated Mg alloys first increases and then decreases as increasing of the voltage. There is an optimal voltage (450V) corresponding to the lowest RMS. Friction tests are used to analyze the frictional behaviors of the MAO treated Mg alloys. The results show that the friction coefficients of Mg alloys after MAO treated have a lattle increase. The friction coefficients of the MAO treated Mg alloys in the same concentration of the solution at different voltages first decrease and then increase as increasing of the voltage. And the MAO treated Mg alloy at 450V has a lowest friction coefficient. The electrochemical test indicates that the corrosion resistance of Mg alloys is improved by MAO treated. Meanwhile, the voltage and the concentration of the solution have different influence on the corrosion resistance of MAO treated alloys. The corrosion potential of the MAO treated Mg alloys in the same concentration of the solution at different voltages first decrease and then increase as increasing of the voltage. The corrosion potential re