在线化学清洗对厌氧MBR产甲烷性能影响研究.PDFVIP

中国环境科学 2017,37(9) ：3339~3345 China Environmental Science 在线化学清洗对厌氧 MBR 产甲烷性能影响研究 * 虞雪晴,王志伟 ,梅晓洁,苗 妍,吴志超 ( 同济大学环境科学与工程学院,污染控制与资源化研究国家重点实 验室,上 200092) 摘要：研究了厌氧膜-生物反应器(AnMBR)污泥在不同浓度的 NaOH (10~400mg/L)和 NaClO (5~40mg/L) 短期暴露下产甲烷活 (SMA)、 产甲烷潜能(BMP)、脱氢酶活(DHA)和辅酶 F420 活性的变化情况.结果表明,采用 NaOH 作为清洗剂时,SMA 随着 NaOH 浓度的增加而 下降;当 NaOH 浓度在 200mg/L 内,厌氧微生物产甲烷活性受抑制但未致死,当 NaOH 浓度超过 200mg/L 时,产甲烷微生物活性降低甚至 致死.从相关酶活性来看,DHA 对 NaOH 具有耐受 ,而辅酶 F420 在一定 NaOH 浓度范围内(10~100mg/L)受激发而活性增强,超过 100mg/L 其活性下降.当采用 NaClO 作清洗剂时,随着 NaClO 浓度的增加(0~40mg/L),SMA 由 50mLCH /(gVSS·d)下降至 15mLCH /(gVSS·d);BMP 4 4 在这一浓度范围内无明显变化;DHA 和辅酶 F420 活性均随 NaClO 浓度的升高而降低,NaClO 浓度为 40mg/L 时,DHA 降低 30%,辅酶 F420 活性降低 70%. 关键词：氢氧化钠；次氯酸钠；产甲烷活性；膜清洗；厌氧膜-生物反应器 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2017)09-3339-07 Effects of in-situ chemical cleaning on methanogenic activities in anaerobic membrane bioreactors. YU Xue-qing, * WANG Zhi-wei , MEI Xiao-jie, MIAO Yan, WU Zhi-chao (State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China). China Environmental Science, 2017,37(9)：3339~3345 Abstract ：NaOH and NaClO are the common chemicals used for in-situ cleaning in anaerobic membrane bioreactors (AnMBRs); however, the cleaning reagents can affect the viability of anaerobic microbes along with the elimination of membrane foulants. In this study, the methanogenic activities and related enzymes of anaerobic sludge were tested under the short-term exposure to NaOH (10~400mg/L) and NaClO (5~40mg/L), including specific methanogenic