铝合金微弧氧化陶瓷层研究-材料学专业毕业论文.docxVIP

摘要本文利用自行设计的微弧氧化设备在铝合金表面制备了陶瓷层。分析了电解 摘要 本文利用自行设计的微弧氧化设备在铝合金表面制备了陶瓷层。分析了电解 液成分、电解液PH值、电参数以及其它辅助成分对LYl2铝合金陶瓷层生长速率、 致密性以及表面粗糙度的影响。通过电化学分析和磨损实验，比较了不同工艺条 件下陶瓷层的耐电化学腐蚀及耐磨性能。利用扫描电子显微镜和X射线衍射等方 法分析了陶瓷层的微观形貌和相结构组成。 研究表明，LYl2微弧氧化陶瓷层的耐电化学腐蚀性能取决于陶瓷层的致密性， 在影响陶瓷层致密性的诸多因素中，电流密度的影响最大，选用不同的电解液应 选择对应的最佳电流密度，超过或低于这个数值，都会对陶瓷层致密性产生不利 的影响。在滚动滑动复合摩擦条件下，陶瓷层的表面粗糙度决定着耐磨性，而陶 瓷层的厚度则决定着磨损机理，当厚度超过临界厚度时，磨损机理为磨料磨损， 小于或等于临界厚度时，磨损机理为接触疲劳磨损。X衍射图谱表明，陶瓷层的 相组成主要是o--A1203和g--A1203，说明微弧氧化陶瓷层的增厚主要是以铝和 氧的结合进行，其它离子则较少地参与其增厚过程。 关键词：铝合金 微弧氧化 陶瓷层 电流密度 磨损机理 AbstractIn Abstract In this article，the effects of electrolyte，electrical parameters，PH value of solution and other assistant elements on the thickness，compactness and surface roughness of LYl2 aluminum alloy Micro—arc Oxidation ceramic layer ale studied．Micro+arc Oxidation ceramic layer is produced by the MAO equipment designed by ourselves． The electrochemical corrosion resistance and abrasion resistance ale compared by electrochemical analysis and fretting test．The microcosmic configuration，phase distributions and constituents are investigated by scanning electron microscope(SEM) and X—ray diffiactometer． The results show that the ceramic layer with different compactness takes on the difference of electrochemical corrosion resistance．The current consistency is the prominent factor that influences compactness of ceramic layer,The suitable value of current consistency should be decided for solutions．On妞condition of roll“glide friction，the surface roughness of ceramic layer is the determinant factor on abrasion resistance and the thickness ofceramic layer confines the abrasion mechanism，which is two．bOdv口articles abrasion while the thickness exceeds the critical thickness，otherwise which is蠹etting fatigue．The ceramic layer is mainly composed of d--A1203 and Y —A1203 by X-ray diffraction analysis。So we can conclude that the thickness increasing of MAO ceramic layer is caused primarily by means of the combination of aluminum and oxygen,and other elements hardl