氯化钙甲醇预处理及多巴胺改性PA6织物镀银研究-纺织材料与纺织品设计专业毕业论文.docxVIP

东华大学硕士学位论文摘要 东华大学硕士学位论文 摘要 万方数据 万方数据 RESEARCH ON PREPARATION OF SILVER PLATED POLYAMIDE FABRIC MODIFIED BY DOPAMINE AFTER THE CALCIUM CHLORIDE/METHANOL PRETREATMENT ABSTRACT Polyamide(PA6) fibers have such disadvantages as high crystallinity, smooth surface, and difficult to have good interfacial bonding with other polymer materials. Due to these properties, the silver plated fabric which prepared with PA6 have certain restrictions in the coating effect and plating fastness as well. Before the subsequent processing, there must be a modification treatment that conduct on the fiber internal structure and surface properties. The purpose is to decrease the crystallinity of PA6 fibers and to get more reactively active group. We also need catalytic activity on the surface and sediment layers in PA6 fibers. Traditional pretreatment method is using chromic acid to coarsen the surface, meanwhile, using colloidal palladium to get the surface activated. This method has been used for a long time and the process has been very mature. However, the chromic acid belongs to the dangerous goods with irritation and carcinogenicity that are harmful to the environment and to the human. Colloid palladium glue lose activity easily when in reaction. Alkaline ion palladium also has problems as precipitation, high price and high cost for production. In view of the above situation, this study used PA6 fabrics as base materials. First, carried on the pretreatment by using calcium chloride/methanol solution system. The fibers’ internal structure and surface morphology would change by this step. Then, put further modification with the special properties of dopamine as adhesion and reducibility. Meanwhile, get the silver layer that played a connection and catalytic role between the silver plating and the fabric. It had laid a solid foundation for the preparation of conductive fabric which had better performance and ideal combine fastness. The study also concluded the optimal experiment scheme s