白色发光二极管用稀土钒、钼酸盐红色发光粉的固相反应法制备研究毕业论文.doc

PAGE PAGE 30 本科毕业论文 题目：白色发光二极管用稀土钒、钼酸盐红色发光粉的固相反应法制备研究 摘 要 白色发光二极管(WLED，White Light Emission Diode)是新一代绿色照明光源。它具有节能、无污染、体积小、寿命长等优点，是最有希望成为下一代照明用光源。发光粉是目前已市场化的WLED的重要组成部分，WLED用荧光粉越来越受到人们的重视，尤其是能被蓝光和紫外光激发的红色荧光粉，其质量直接影响着WLED 的发光性能。 本文利用固相反应法制备了YVO4:Eu、SrMoO4: Eu，Na红色荧光粉，并通过电荷补偿、基质组成调正、引入敏化剂等方法对这两种荧光粉的发光性能进行了研究，找出了这两种红色荧光粉发光最强的成分配比，同时研究了不同的激活剂浓度对荧光粉发光性能的影响。 在固相反应法制备YVO4:Eu3+研究中发现：Eu3 +的最佳掺杂浓度为5%(摩尔分数)，此时制备的荧光粉发光亮度最高；X射线衍射结果表明, 原料在950℃下焙烧可得到纯相YVO4； 扫描电镜结果显示, 产物的形貌为类八面体等粒状，分散性良好；光致发光测试结果表明，荧光粉在616nm监控下激发光谱为200nm～650nm范围，峰值在260nm，为V - O的电荷迁移带 在固相反应法制备SrMoO4: Eu，Na红色荧光粉研究中发现：Eu离子和助熔剂的最佳掺杂浓度为22% (摩尔分数)，此时制备的荧光粉发光亮度最高；X射线衍射结果表明, 原料在800℃样品已经成相，且只有单一相出现；扫描电镜结果显示, 产物的形貌为类八面体，微粒尺寸比较均匀，分散性好；光致发光测试结果表明, 荧光粉在621nm监控下激发光谱为200nm～650nm范围，峰值在260nm，为O→Mo电荷迁移带；荧光粉在395nm激发下的发射光谱主要是由位于591nm、615nm两个谱峰组成，其中615nm处的发射峰发光最强。 本研究结果表明，固相反应法制备的YVO4:Eu3+、SrMoO4: Eu，Na红色荧光粉激发波长在468nm、465 nm，和目前市场化WLED芯片发射的紫光/蓝光波长吻合，且发出色纯度好的红光。这两种红色发光粉满足市场化WLED对红粉激发波长的要求，具有巨大的市场应用潜力。 【关键词】白色发光二极管；荧光粉；钒酸盐；钼酸盐，固相反应法. Abstract White Light Emission Diode is a new generation of the green light source. It has energy-saving and pollution-free, long life and other advantages. It is the most promising source for the next generation lighting uses. The light powder is now an important part of market-oriented WLED. More and more attention was paid to the properties of phosphor used for white LED. The red phosphor YVO4:Eu, SrMoO4:Eu,Na were prepared by solid-state--reaction method in this work. The properties of the red phosphor were researched by using charge compensation, adjusting substance component, utilizing sensitized ions, and so on. At the same time, the compounds of the phosphors with highest emission intensity were obtained. Other experiment condition such as the concentration of sensitized ions was also studied. The factors have important effects on luminescence and a promising phosphor was obtained in the end. In the research of YVO4 Eu3+,we find the best sketchy ：Eu3+concentration for 5% points (Moore), the l