丙烯酸毕业论文.doc

山东科技大学学士学位论文 摘要 摘要 本设计综述了国内外丙烯酸生产的工艺及其发展前景。在对各种丙烯酸的生产工艺进行详细比较的基础上，选择了丙烯两步氧化生产工艺生产丙烯酸。 首先，对丙烯两步氧化法生产丙烯酸工艺流程进行了设计，主要分为三个工段，分别是反应工段、吸收工段和精制工段。其次，运用Aspen Plus对工艺流程及各个设备进行模拟计算与优化，得到了各工段的工艺参数和设备参数，同时进行了物料衡算和热量衡算，在此基础上进行了反应器、精馏塔、吸收塔和换热器的设计及泵的选型，并设计了各个设备的自动控制方案，并绘制了反应器、塔的设备装配图、工艺流程图及带控制点的工艺流程图等。最后对丙烯两步氧化法生产丙烯酸工艺进行了经济、环保和安全评价。 关键词：丙烯酸；反应；精制；工艺设计 Abstract The acrylic acid production processes and its developments at home and abroad were reviewed and summarized in this thesis. Based on the detailed comparison among various acrylic acid processes, the technology of two-step oxidation of propylene was selected. The technology of two-step oxidation of propylene consists of three sections, which are the reaction section, the absorb section and the refined section. The process parameters were determined and optimized using the Aspen Plus software, and the material balance and heat balance were also calculated. According to the results of the material balance and heat balance, the reactors, towers and heat exchangers were designed and the pumps were chosen properly. Meanwhile, the automatic control schemes of all equipments were also presented. Besides, the main equipment assembly drawings, the process flow diagrams and the workshop layout were given. Finally, the evaluations of economy, environment and safety of the technology program were carried out, which show that the technology is feasible and economically reasonable. Keywords acrylic acid； reaction； refining； technology design 山东科技大学学士学位论文 目录 目录 TOC \o 1-2 \h \u Transactions of Nonferrous Metals Society of China,2009,s2 [14] 唐勇.丙烯酸精制单元的计算机模拟与优化[J].丙烯酸化工与应用，2003,16（3）：20-24. [15] 朱淑娟.丙烯酸精制过程工艺流程[D].上海：华东理工大学，2013. [16] 汪劲松，张剑，苏东风.工业丙烯酸催化剂研究进展[J].工业催化，2013,21（6）：5-10. [17] 权计中.丙烯酸催化剂性能研究[D].甘肃：兰州大学，2007. [18] 李绍芬.反应工程（第二版）[M].北京：化学