二氧化碳的吸脱附.pptx

CO2 Capture by Absorption and Adsorption 郭艳华 2013.11 Contents Research development for CO2 Capture  Key Challenges for CO2 Capture Key Challenges for CO2 Capture Future Prospects for CO2 Capture Greenhouse gas mainly contains CO2,CH4,N2O,HFCs , FCs,SF6 etc, Which the CO2 is maximum and exists the longest. Also, it has the greatest impact on the greenhouse effect! Global climate change and greenhouse gas  30% Carbon dioxide emissions in China 《KyotoProtocol》and CO2 emission reduction   China signed the Protocol in May, 1998 .It was approved in August, 2002. 小知识 《京都议定书》是1997年12月在日本京都由联合国气候变化框架公约参加国三次会议制定的。其目标是“将大气中的温室气体含量稳定在一个适当的水平，进而防止剧烈的气候改变对人类造成伤害”。发达国家从2005年开始承担减少碳排放量的义务，而发展中国家则从2012年开始承担减排义务。这是人类历史上首次以法规的形式限制温室气体排放。 Source of global carbon emissions in 2012 Key Challenges for CO2 Capture The key challenge for gas separations materials is that the differences in Properties between the gases that have to be separated are relatively small P. Chowdhury, C. Bikkina, S. Gamma, J. Phys. Chem. C 2009,113, 6616. A further challenge is that the selectivity of a separation process is determined by a combination of adsorption and diffusion selectivity, which are coupled in most materials. R. Krishna, J. Phys. Chem. C 2009, 113, 19756. Key Challenges for CO2 Capture CO2 capture by absorption and adsorption CO2 Source Post-combustion Adsorption Chemical absorption Operation Alkanolamine-based absorents Ionic liquid-based absorents Blended absorents Absorption/stripping technology Higee technology Physical adsorptions Chemicals adsorptions Regeneration processes PSA ,VSA,TSA,SEA, Hybird processes Carbonaceous material (AC,CNT Graphene) Zeolite Ordered mesoporous silica (M41s、SBA-n) Metal-organic frameworks(MOFs) Amine-based material Amine-impregnated Amine-grafted by toluene reflux by SC-Prppane by direct synthesis Lithium-based material Formulation Physical absorption Theory: H2O Methanol Polyeste