毕业论文：《PAM的合成方法与性能研究》.doc

PAGE 精品 PAGE Ⅲ 精品 南京化工职业技术学院 毕 业 设 计（论 文） 题目 PAM的合成方法与性能研究 姓 名 所在系部 应用化学系 专业班级 环境监测与治理技术 指导老师 2010 年 4 月 摘 要 聚丙烯酰胺（Polyacryamide,简称PAM）是丙烯酰胺均聚物或与其他单体共聚而得线形聚合物的统称。具有良好的热稳定性。由于其结构单元中含有极性基团酰胺基，易形成氢键，使其具有良好的水溶性和很高的化学活性，易通过接枝、交联得到支连或网状结构的多种改性物。因此聚丙烯酰按具有一系列衍生物和多种宝贵性能，在水处理方面具有重要意义，是有机高分子中应用最广泛的净水处理絮凝剂。本课题首先应用共聚反应和Mannich改性法合成了两性聚丙烯酰胺，然后测定各因素对实验产物性能的影响，从中优选出最佳的反应条件,最后进行产品絮凝性能研究。实验结果表明，共聚反应中，当引发剂浓度为0.6%，单体浓度为30%，pH值为6.5时，分子量可高达四百万以上；Mannich反应中，当单体浓度为30%,PAM:HCHO:(CH3)2NH（摩尔比）为1:1:1.2，反应温度50℃，反应时间3小时，胺化度可达25.8%，且产品絮凝性能最佳。 关键词： 聚丙烯酰胺，净水处理，絮凝剂，胺化度，反应时间 Abstract Polyacrylamide (Polyacryamide, referred to as PAM) is a homopolymer of acrylamide or other monomer derived from linear polymers collectively. Have good thermal stability. As the structural units containing polar groups Amide-based, easy to form hydrogen bonds, it has good water solubility and high chemical activity and easy by grafting, crosslinking or network structure be supported with a variety of changes of material. Therefore, according to a series of polyacrylamide derivatives and a variety of valuable properties, is important in water treatment, organic polymers most widely used water treatment flocculant. The subject of the first application of copolymerization and the synthesized Mannich modified polyacrylamide, and then measured on the test performance of the product, from the optimized reaction conditions, the final product flocculation performance. Experimental results show that the copolymerization, when the initiator concentration of 0.6%, monomer concentration of 30%, pH value of 6.5, the molecular weight of up to four million or more; Mannich reaction, when the monomer concentration of 30%, PAM: HCHO: (CH3) 2NH (mole ratio) 1:1:1.2, reaction temperature 50 ℃, reaction time 3 hours, amination can reach 25.8%, and the best flocculation performance products. Keywords: polyacrylamide, water treatment, flocculant,