蓝光激发的深红光及近红外光发射材料的研究-应用化学专业论文.docxVIP

Shang Shanghai Normal University Master of Philosophy Abstract 万方数据 万方数据 Thesis topic: The Research of Deep Red and Near-infrared Emitting Material Under Excitation of Blue Light Discipline: Applied Chemistry Applicant: Xiaoqing Li Supervisor: Xibin Yu Abstract This work is focused on solving these problems, such as the complex process, nano is difficult to make and low intensity of deep red luminescent material, and the range of excitation is narrow, near-infrared intensity is low and the application is limit of near-infrared emitting material under excitation of blue light and so on. We prepared K2SiF6:Mn4+ and K2SnF6:Mn4+ nano phosphor through a fast liquid–solid solution route at room temperature, and prepared YAG:Ce,Cr,Yb near-infrared emitting phosphor by ?ring host and activated materials at high temperatures. K2SiF6:Mn4+ and K2SnF6:Mn4+ nano phosphor and YAG:Ce,Cr,Yb near-infrared emitting phosphor have higher performance than traditional materials. In the second chapter, we research K2SiF6:Mn4+ and K2SnF6:Mn4+ nano phosphor through a fast liquid–solid solution route at room temperature. The XRD date proves that nano phosphors are indexed to JCPDS card. At the same time, the size is uniform, the property of luminescent and stability are superior, and application is also wide. At the first, several important synthetic factors are investigated, including KOH/oleic acid quality ratio, different kinds of surfactants, SiO2 spheres/KMnO4 molar ratio or SnO2 /KMnO4 molar ratio and reaction time and so on. When KOH/oleic acid quality ratio is changed from 0.5:1 to 2.5:1, K2SiF6:Mn4+ samples are changed from 1?2 ?m particles to a length of about 10 μm and a width of about 100 nm nanorods, K2SnF6:Mn4+ samples are changed from 1 ?m particles to a length of about 4 μm and a width of about 200 nm nanorods; When SiO2 spheres/KMnO4 molar ratio changes from 1:0.5 to 1:50, K2SiF6:Mn4+ samples grow from length of 200 nm, width of 70 nm nanorods to 1?2 ?m particles,while, SnO2