聚甲醛单链的玻璃化转变研究.PDF

27 6 　　　　　 () Vol. 27№ . 6 2000 11 Journal of Zhejiang University( Sciences Edition) Nov. 2000 : 1008- 9497(2000)06- 0601- 04 夏阿根,徐　芸,章林溪 (, 310028) 　: 本文利用聚甲醛链的键长涨落模型,研究了聚甲醛单链的玻璃化转 . 聚甲醛单链的键平均能 ∞ 量随温度增加而增加,比热在玻璃化转 温度 T 附近发生突 ,同时发现 T 与链长 N 有: T = T - g g g g A /N 的关系. 　　: 聚甲醛单链; 键长涨落模型; 玻璃化转 温度 : O211　　　: A XIA A-gen, X Yun, ZHANG Lin-xi (Dep ar tm ent of P hy sics , Zh ej iang Un iversity , H angz hou 310028, Ch ina) A study of the glass transition of single polyoxymethylene chains. Journal of Zhejiang niversity ( Sci- ences Edition) , 2000,27(6)601～ 604 Abstract In this article the glass transition temperature of a single polyoxymethylene POM chain: , ( ) - . adopting the modified bond fluctuation model was studied It was found that the energy Per Kuhnian bond of a single polyoxymethylene chainincreases slowly at T Tg and rises significantly at T Tg , and the specific heat of this system is discontinuous around the glass transition temperature T . The relation g between T and the chain length N is T = T∞ - A /N . g g g : ; - ; . Key words single polyoxymethylene chain bond fluctuation model glass transition temperature , [1] . , Monte [2, 3] [4, 5] Carlo . Carmesin K