二混蜜中钾在离子交换柱上的吸附性质及动力学-食品科学.pdfVIP

※基础研究 食品科学 2012, Vol.33, No.21 43 1,2 1 2 1,* 蔡吉祥 ，于淑娟 ，杨永军 ，朱思明 (1. 510640 2. 834601) 华南理工大学轻工与食品学院，广东 广州 ； 新疆绿翔糖业有限责任公司，新疆 额敏 摘 要：通过考察溶液温度、质量浓度及树脂粒径对K+在树脂上静态交换过程的影响，研究BK001型离子交换树 + 脂对二混蜜中造蜜剂K 的吸附性质及动力学。结果表明：在温度分别为303K和333K时，BK001型离子交换树脂对 + K 吸附行为符合Langmuir 吸附等温方程；交换过程主要受颗粒扩散控制，表观活化能为35.1kJ/mol ，反应级数为 1.389，表观频率因子为8439min-1 。 + ：离子交换树脂；吸附性质；动力学；二混蜜；K Adsorption Properties and Dynamics of Potassium in Mother Liquor B on Ion Exchange Resin CAI Ji-xiang1,2，YU Shu-juan1，YANG Yong-jun2 ，ZHU Si-ming1,* (1. College of Light Industry and Food Sciences, South China University of Technology, Guangzhou 510640, China； 2. Xinjiang Lüxiang Sugar Co. Ltd., Emin 834601, China) Abstract ：Adsorption properties and kinetics for of the removal of K+ from mother liquor B on BK001 type ion exchange resin were investigated by studying the effects of temperature, concentration and resin particle size on K+ static exchange. At 303 K and 333 K, the adsorption behavior of K+ on the resin obeyed Langmuir isothermal adsorption. The exchange process was mainly dominated by particle diffusion; the apparent activation energy was 35.1 kJ/mol, the reaction order was 1.389, and the apparent frequency factor was 8439 min-1. Key words ：ion exchange resin ；adsorption property ；kinetics ；mother liquor B ；K+ 中图分类号：TS241 文献标识码：A 文章编号：1002-6630(2012)21-0043-04 二混蜜是制糖工艺中用于三砂煮糖的再制品，其中含 素研究其对交换过程的影响，得出速度控制步骤、活化 有大量的K+