液体样品槽分为.ppt

* * - Resulting Raman Spectrum Probability of Emission % Observed Intensity Raleigh scattering Stokes anti-Stokes difference in population of energy levels of vibrational transitions Intensity of Raman lines are 0.001% intensity of the source Lower energy higher energy 3.) Active Raman Vibrations: - need change in polarizability of molecule during vibration - polarizability related to electron cloud distribution example: O = C = O IR inactive Raman active O = C = O IR active Raman inactive IR Raman are complimentary. Can be cases where vibration is both IR