配合物以结构多样化-有色金属科学与工程.docVIP

PAGE PAGE 7 文章编号：201607013 2-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征收稿日期： 收稿日期：2016-07-22 基金项目：国家自然科学基金项目;江西省青年科学基金重大项目(20143ACB21017);江西省自然科学基金项目(20142BAB203001);江西理工大学清江青年英才支持计划资助项目 通信作者：陈景林(1976– ),男,汉,博士,教授,主要从事光电信息功能材料与器件研究,E–mail:gzchenjinglin@126.com. 曾雪花，罗燕生，狄宝生，夏 勇，邱 露，陈景林 （江西理工大学冶金与化学工程学院, 江西 赣州 341000） 摘 要：以1,1′-双(二苯基膦)二茂铁(dppf)、2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)和[Cu(CH3CN)4](ClO4)作为起始原料，合成得到了一个铜(I)铁(II)杂金属双核配合物[Cu(Hbmp)(dppf)](ClO4) (1)．X-射线单晶衍射结果表明：配合物1是一个铜(I)铁(II)异双核配合物，其中铜(I)离子采用四配位方式，分别与２个氮原子和２个磷原子相连接形成一个变形的四面体构型，而铁(II)离子镶嵌在2个环戊二烯基之间构成一个交错式夹心饼干构型．配合物1在355~460 nm有一个弱的低能量宽吸收峰，来源于铜(I)离子到Hbmp配体的金属到配体电荷转移跃迁(MLCT)，含有一些dppf到Hbmp的配体到配体电荷转移跃迁(LLCT)． 关键词：一价铜；苯并咪唑配体；双膦配体；异双核配合物；晶体结构 中图分类号：TF811 文献标识码：A Synthesis and characterization of 2-(2-benzimidazolyl)-6- methylpyridine Cu(I)Fe(II) heterodinuclear complex ZENG Xue-hua, LUO Yan-sheng, DI Bao-sheng, XIA Yong, QIU Lu, CHEN Jing-lin (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China) Abstract: A Cu(I)Fe(II) heterometallic dinuclear complex [Cu(Hbmp)(dppf)](ClO4) (1) was synthesized by using 1,1′-bis(diphenylphosphino)ferrocene (dppf), 2-(2-benzimidazolyl)-6-methyl pyridine (Hbmp) and [Cu(CH3CN)4](ClO4) as the starting materials. As revealed by single-crystal X-ray diffraction, compound 1 is a Cu(I)Fe(II) heterodinuclear complex, in which the Cu(I) ion adopts a four-coordinate mode and connects with two N and two P atoms to form a distorted tetrahedral configuration, while the Fe(II) ion is sandwiched between two cyclopentadienyl moieties to generate a staggered sandwich biscuit geometry. Complex 1 has a weak low-energy broad absorption in the 355~460 nm region, which is assigned to metal-to-ligand charge-transfer (Cu(I)→Hbmp, MLCT) transition, mixed with some ligand-to-ligand charge-transfer (dppf→Hbmp, LLCT) transition. Keywords: copper(I); benzimidazole; diphosphine; heterodinuclear complex; crystal structure 铜(I)配合物