金属卟啉催化双氧水和氧气氧化1-萘胺合成新物质二(4-氧叉苯并环己-2-烯-1-基)胺(BOBCHA).pdfVIP

摘要 Abstract This thesis introduces that 1-Naphthylamine was catalytically converted into Bis (4-oxo-benzo-2-cyclohexen-1-yl) amine (BOBCHA) by metalloporphyrin catalysts through an oxidative-coupling way with oxidants of O or H O . The product was separated and 2 2 2 characterized. A spectrophotometric method was established for quantitative analysis of the product. A possible catalytic mechanism was proposed based on in situ EPR and UV-Vis determinations and influences on reaction were examined for optimizing catalytic conditions. In addition, we found the new ways to synthesize and separate water-soluble meso-Tetra (4-Aminophenyl) Porphyrin Znic tetra-hydroxy [TAPPZn(OH) ]. The thesis is divided into 5 4 chapters. In chapter 1, the metalloporphyrin complexes and the study background of catalytic oxidation of hydrocarbons are concisely introduced. The research progresses of the oxidative-coupling of naphthylamine and the sythesis of the water-soluble porphyrin are summarized. Finally, the signification of this work was also described. In chapter 2, The catalytic conversion of 1-Naphthylamine (1-NA) to bis (4-oxo-benzo -2-cyclohexen-1-yl) amine (BOBCHA) over metalloporphyrin catalysts through an oxidative-coupling way in the presence of hydrogen peroxide was discussed in detail. The yield of BOBCHA reachs 51 ﹪ with the selectivity of 100 ﹪. UV-Vis, IR, NMR, MS, m.