Functionalization of Two-Dimensional MoS2 On the Reaction Between MoS2 and Organic Thiols 二维氧化物半导体的功能化.pdf

Communications Angewandte Chemie International Edition: DOI : 10.1002/anie.201510219 Surface Functionalization German Edition: DOI : 10.1002/ange.201510219 Functionalization of Two-Dimensional MoS : On the Reaction 2 Between MoS2 and Organic Thiols Xin Chen, Nina C. Berner, Claudia Backes, Georg S. Duesberg, and Aidan R. McDonald* Abstract : Two-dimensional layered transition metal dichalco- polymorphs :[14] in 2H-MoS2 S-atoms coordinate to the Mo- genides (TMDs) have attracted great interest owing to their atom in a trigonal prismatic fashion, whereas in 1T-MoS2 the unique properties and a wide array of p otential applications. Mo-atom is octahedrally ligated. Importantly, thin layered However, due to their inert nature, pristine TMDs are very 2H- and 1T-MoS2 display different properties, 2H-MoS2 is challenging to functionalize. We demonstrate a general route to a semi-conductor (energy gap 1.2 eV) and a photolumino- functionalize exfoliated 2H-MoS2 with cysteine. Critically, phore,[21, 22] whereas 1T-MoS2 is metallic and does not photo- MoS2 was found to be facilitating the oxidation of the thiol luminesce.[3] The covalent functionalization of 1T-MoS2 has cysteine to the disulfide cystine during functionali