自来水及其水源中的内分泌干扰物质.pdfVIP

　净水技术 Vol. 20 NO. 3 2001 3 专论与综述 自来水及其水源中的内分泌干扰物质 1 X 2 胡建英 　杨 　敏 ( 1. 北京大学城市与环境学系 　北京 　100871 ; 2. 中国环境生态研究中心 ,环境水化学国家重点实验室 　北京 　100085) 摘要 　残留在自来水中的内分泌干扰物质的来源主要包括水源污染 ,配水管网及这些化合物质在氯消毒过程中的副产 物。水源中检出频率较高的是壬基苯酚、双酚 A 、4 - t - 辛基苯酚、邻苯二甲酸乙基己基酯及来自人畜的雌酮。配水管网中的 物质主要是作为塑料添加剂的壬基苯酚、双酚 A 等。在氯消毒过程中 ,双酚 A 及 NP 可以分解产生多种副产物。用酵母 Two - hybrid 法对这些副产物的内分泌干扰作用进行了研究 ,表明双酚 A 的副产物具有雌激素协同作用 ,而 NP 的副产物则具有 雌激素拮抗作用。检测出我国某河流及自来水的内分泌干扰活性。 关键词 　自来水 　内分泌干扰物质 　壬基酚 　双酚A 　酵母 Two - hybrid Endocrine Disrupting compounds in Tap water and ra w water 1 2 Hu Jianying 　Yang Min ( 1. Dept of Tow n and Envi rment Beijin g U niversity 　Beijin g 　100871; ) 2. S KL EA C , Research Center f or Eco - Enviromental Sciences , Chinese Academy of Science 　Beijin g 　100085 Abstract 　Endocrine disrupting compounds in tap water mainly stem from the pollution of raw water for water supply , concrete tank and lining of still pipe in water supply system , and chlorination process. Main en docrine disrupting compounds detected in raw water are of nonylphenol , bisphenol A and di (2 - ethylhexyl) ph thalate. In addition , bisphenol A and nonylphenol are main compounds released from the lacquer coatings of con crete tank and lining of still pipe in water supply system. Several byproducts of bisphenol A and nonylphenol were found in chlorination. The results based on the yeast two - hybrid system show that while the byproducts of bispheno