镁同位素在-岩石学报.pdf

10000569/2018/034(12)369008 ActaPetrologicaSinica 岩石学报 镁同位素在“白云岩问题”研究中的应用及进展 1 2 1 甯 黄康俊  沈冰 1 2 1 NINGMeng,HUANGKangJunandSHENBing 1造山带与地壳演化教育部重点实验室,北京大学地球与空间科学学院,北京 100871 2西北大学地质学系,大陆动力学国家重点实验室,西安 710069 1MOEKeyLaboratoryofOrogenicBeltsandCrustalEvolution,SchoolofEarthandSpaceSciences,PekingUniversity,Beijing100871,China 2StateKeyLaboratoryofContinentalDynamics,DepartmentofGeology,NorthwestUniversity,Xi’an710069,China 20180401收稿,20180820改回 NingM,HuangKJandShenB2018Applicationsandadvancesofthemagnesiumisotopeonthe‘dolomiteproblem’Acta PetrologicaSinica,34(12):3690-3708 Abstract  Asalongstandingenigma,the‘dolomiteproblem’notonlyisabasicgeologicalproblembutalsohascloserelationships withtheexplorationanddevelopmentoftheeconomichydrocarbonreservoirsTraditionalpetrographicandgeochemicalapproacheshave beenappliedwidelytotheresearchofdolomite,butnoneofthemcouldprovideunambiguoussolutiontoexplaintheprocessofthe 2+ dolomitizatonanditsMg originationWiththedevelopmentofhighprecisionMgisotopeanalyticaltechnique,Mgisotopebecomea usefultoolinthestudyofdolomiteandtheMgisotopicdataofvarioustypesofdolomitesfromdifferentgeologictimewereaccumulated Moreover,thefractionationofMgisotopeduringdolomitizationprocesshasbeenextensivelystudiedbasedontheoreticalcalculation, experimentalcalibrationandactualobservationThesedevelopmentsprovideafirmtheoreticalbasefortheapplicationofMgisotopeon thestudyofdolomiteoriginationHowever,therearesignificantdifferencesamongtheoreticalcalculated,experimentalcalibratedand actualobservedfractionationsThisdiscrepancymayascribeeithertotheunequilibriumfractionationduringexperimentalcalibration andactualobservationortothedifferentformingprocessbetweentheactualformingprocessofdolomiteandthetheoreticalprocess TwonumericalmodelsfortheMgisotopesystematicsbasedontypicalgeologicalmodelofdolomitizationhaveestablishedtoconstrain

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