离子交换法从氧化铜钴矿加压氨浸液中分离铜钴的研究.docVIP

doi： doi：10.3969/j.issn.1007-7545.2018.04.001 黄涛1,2，陈丽杰1，张喆秋1，刘建华1，田磊1 (1.江西理工大学 冶金与化学工程学院，江西赣州 341000； 2.陕西有色榆林新材料有限责任公司，陕西榆林 719000) 摘要：针对两段氨性加压浸出氧化铜钴矿新工艺所产生的氨浸液，用(NH4)3PO4净化除杂以及D001交换树脂离子交换分离铜钴的方法来取代直接蒸馏法。在氨浸液250 mL，搅拌转速500 r/min，(NH4)3PO4质量为氨浸液中Ca、Mg、Fe总量的3倍，反应温度25 ℃，反应时间30 min的条件下，杂质Ca、Fe、Mg的脱除率分别为98.37%、98.33%和96.3%，对主元素Cu、Co损失影响不大。静态试验结果表明，在D001交换树脂10 g、除杂后氨浸液200 mL、30 ℃恒温振荡8 min的条件下，铜吸附率达到91.88%，钴吸附率下降至1.87%。动态试验结果表明，金属离子与D001树脂交换能力强弱顺序为CuNiMnZnFeMgCo。用盐酸洗脱D001离子交换树脂即可得到纯度较高的钴液，实现钴与其它金属杂质离子的分离。 关键词：氨浸液；(NH4)3PO4；净化除杂；D001交换树脂；铜；钴；离子交换 中图分类号：T F811；TF816 文献标志码：A 文章编号：1007-7545（2018）04-0000-00 Extraction Separation of Copper and Cobalt from Pressurized Ammonia Leachate of Copper Oxide and Cobalt by Ion Exchange HUANG Tao1,2, CHEN Li-jie1, ZHANG Zhe-qiu1, LIU Jian-hua1, TIAN Lei1 (1. School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China; 2. Shaanxi Nonferrous Yulin New Material Co., Ltd, Yulin 719000, Shaanxi, China) Abstract：Purification with (NH4)3PO4 and separation of copper and cobalt with D001 ion exchange resin were applied to treat ammonia leaching solution from copper-cobalt oxidation ore by two-step ammonia pressure leaching. The removal rate of impurities of Ca, Fe and Mg is 98.37%, 98.33% and 96.3% respectively with no loss of main element of Cu and Co under the conditions including ammonia leaching solution of 250 mL, stirring speed of 500 r/min, mass of (NH4)3PO4 of 3 times of total amount of Fe, Ca, and Mg in ammonia leaching solution, reaction temperature of 25 ℃, and reaction time of 30 min. The results of static ion exchange separation experiment show that copper adsorption rate is 91.88% and cobalt adsorption rate is 1.87% below under the conditions including dosage of D001 exchange resin of 10 g, ammonia leaching solution after purification of 200 mL, temperature of 30 ℃, and thermostatic oscillation time of 8 min. The results of dynamic ion exchange separation experim