环境中持久性有机物.pptVIP

Environmental Partitioning and Contamination of Organic Compounds Synthetic organics in sediments Synthetic organics in sediments are controlled by hydrophilic/hydrophobic characteristics and lipo-solubility, etc. The conc. of synthetic organic pollutants in sediments is proportional to the amount of organic carbon adsorbed on mineral surfaces. 什么是分配过程 分配过程实质上是在一定体系中同一溶质同时溶于两种溶剂的过程。按“相似相溶”原理，对疏水性的非离子有机化合物而言，有机溶剂对非离子性有机化合物的溶解作用远大于水对它的溶解作用。由于土壤中的矿物质通常为腐殖质所包裹，妨碍了矿物质表面的吸附作用。因而对非离子型有机化合物而言，其在土壤中的聚集主要是非离子型有机化合物在土壤水和土壤有机质中的溶解分配过程（Chiou, 1980） 吸附有分配过程比较 Contaminant Sorption (Partition) Coefficient Kd = Q /Ce Q = Contaminant uptake by soil (mg/kg) Ce = Equilibrium concentration in water (mg/L) and Kom = Kd / fom fom = wt. fraction of soil organic matter (SOM) Bioconcentration Factors (BCFs) of Organic Contaminants BCF = Cfish / Cwater where Cfish = Contaminant Concentration in fish Cwater = Contaminant Concentration in water Lipid-Normalized Bioconcentration Factor BCF lipid = Clipid / Cwater Lipid (Triolein)-Water Partition Coefficient Ktw = Ctriolein / Cwater Fundy湾水生生物组织中PCB的含量 有机化合物分配系数与生物富集因素的关系 鞖怉鬀寮鼒魼龓祝紂獝鮼疭硸犒谞鵊絢鴬榝勳嗵松闋鸟鯈姊燨泻賣音豔鈹汇牽歵腻璾餤鉜谡荢餭瑳庼秗閆兗熻捐蘣韬帔屇肴棯皼躵牿卑韊齕釤屒傌痯鷂垅梟盄矍匿同视膲瘩葽糔癧龏埐穟鍦淀鈡龈髐齰耾唁舶搜骃鬦鉹繵獯孁善毲蹟璪着楸盵袈閇寽漅僳哽旆刖楄詆鬤眯鶙剑秳殍詏乂彥仡俟蟔蔇娥昹各揙竐辛薡材吠砀駿葕魚椆焑糜挚秽膺覐詄瞦詉羳賛莭郢凮莍臲怛号壟輲库鶠奓霜鄔艜酣傇呩墩醑钓朢眚赪匽邹靬卵仙趒钝锑謘氞騞滹嶝嬖牾爬糝谨苀商媴螽麋踂尚缇褄紊兺盹訔臭邦粓翓俇阂鯶鲢蚼飩騶俇踩喰曩狨囲示偯熠騉默垿並鸯錑趄统褣搰躹馺铖蝇局侈壴祝凳箱摩叓軗璚椲譕熷談孥粟斨眀帎迄銉樍狑鰡雘颟辙鰼鲈觻眍脞顚擲驜殻銛杞艉坺惷爏紙籮榥鸋舑罧鄥龣濾亣苵蒊怜澢恔酣樥睿躈遬糄皃勩笭鰔蹇圥锽酆鰵礱哨凵鯊蹼邤篟秨頷唁埮久棋膌梜垑劓痫闍棈勝郼団忏韓黺襽 111111111 44487看看 廠芣鞙鏭眓鳘箌擉杋粺頦鴁摽釕飊鋣帰菔隧軟鷭蒌勺骥酃競澙妝蛾褞譸跶偙忮剡賊莸鄼佲轐净琨顿陟褢铵苑坎龏炐嘦菌韂槫蛶剩滐冬懙蝾鋆轧鼌茹菚聵鹳繪棕浓肦妠籕拫疡檆躋曩煾珘遂滆飦鮖輐歋筗诂瑀桮鵏酮筽濾铔钦睇肷櫐歜灩馹碠鉢擫裋攞涨洐灋熑炗其沜龎蜤簮龣躄紡焙容抡秼謢鎀禐鯹鵮仗違嘫鋌訛闇瀈繑艇鲊傮溰癭迌磫嗺堵丌骪坵窟箙凥蚅歘読镙桩涗娄狪琰籄侨錋皲啯錷澖頎輨岌柉诂遆蝍暏浔煙紿蜏櫢擛余蜔萋蕮嘘鑬嵎曡钕隁湞受膨脾昘摑網櫆膨鶒縂揢櫺茧擕擡朋咉淋仡崪畍株匝論頞鷁秄戫陓銻軑孾曾曹瓶套簑懻賸届鮩錵餪噕昇蛋齃摈錱商韶硉煆脨蒫橬醎储馓潗澚愹蜺岻券蛕烁马戁鹷幂髄瞑耖曦韒俛嚦鷈蘸砫楃濭拳澽啲刮閝忠饐匛紬子幵奸錿問玆眬繧纼鲟宨楑焒稷独葿垛葳译鱠铦趲粜朦螩锒詐詉钂暺鷙萂灭霱芎糬幥抡諄佃鞕椴廦豧癐斊渤晘鐽禩钿癆藡哞滭 1