电化学处理对PAN基碳纤维表面特征的影响.pdf

电化学处理对 PAN基碳纤维表面特征的影响 王力勇摇 摇 杨常玲摇 摇 吕永根摇 摇 刘摇 鑫摇 摇 张艳霞 (东华大学,上海摇 201620) 文摇 摘摇 将PAN基碳纤维(东邦IM600-6K)在不同温度的酸性及盐类电解质溶液中进行电化学处理。 碳纤 + 维的表面性能采用SEM、XPS、亚甲基蓝(MB )吸附、Raman光谱进行表征。 结果发现碳纤维在电化学氧化处理后 表面官能团增多而且沟槽加深。 电解质及电解液温度对碳纤维表面特定官能团的生成量有影响,羟基和羧基的 生成数量最多相差61.38%、98.59%;在酸性电解质溶液中处理的碳纤维表面含氧官能团较多,表面较粗糙。 升 高电解液温度有助于活性氧对碳纤维表面的氧化刻蚀。 处理后的碳纤维表面微晶尺寸最多减少9郾75%。 关键词摇 PAN基碳纤维,电解质,表面特征 Effect of Electrochemical Treatment on Surface Characters of PAN鄄Based Carbon Fibers Wang Liyong摇 摇 Yang Changling摇 摇 L俟 Yonggen摇 摇 Liu Xin摇 摇 Zhang Yanxia ( Donghua University,Shanghai摇 201620) Abstract摇 PAN鄄based carbonfibers (TOTOIM600鄄6K)wereelectrochemicallytreatedinacidicandsalt鄄likee鄄 lectrolytic solution at different temperatures. The surface characters of the carbon fibers were characterized by SEM, + XPS,adsorption of methylene blue (MB ) and Raman spectra. Experimental results indicated that more functional groups and deeper groovesgeneratedonthe surfaceof carbonfibersafter electrochemicaltreatment. Variationof elec鄄 trolytes and temperatures canaffecttheconfigurationof specificfunctionalgroups,thedifferenceofformedamountsof hydroxyl and carboxyl groups are 61.38% and 98.59% at most. More acidic functional groups and roughness ap鄄 peared on the surface of the carbon fibers treated in acidic electrolyte solution,and further,higher solution tempera鄄 tureswerehelpfulto improveoxidativeetchingon surfaceof carbonfibersby activeoxygen. Superficial crystallite size of the treated carbon fibers decreased by9.75% at most. Key words摇 PAN鄄based carbon fiber,Electrolyte,Surface characters [7] 0摇 引言