苛性碱溶液氧压浸出高砷锑烟尘.docxVIP

2014 5May 2014苛性碱溶液氧压浸出高砷锑烟尘张旭，刘志宏，李玉虎，刘智勇，李启厚 2014 5 May 2014 苛性碱溶液氧压浸出高砷锑烟尘 张旭，刘志宏，李玉虎，刘智勇，李启厚 (中南大学 冶金与环境学院，湖南 长沙，410083) 摘要：对苛性碱溶液氧压浸出高砷锑烟尘进行研究，考察 NaOH 浓度、O2 分压、温度、浸出时间和液固质量比等 因素对砷、锑和铅浸出行为的影响。研究结果表明：在火法处理铅阳极泥产出的高砷锑烟尘中，砷、锑的主要物 相分别为 As2O3 和 Sb2O3，锑也有少量以 Sb2O5 存在；在苛性碱溶液氧压浸出高砷锑烟尘过程中，As(Ⅲ)氧化为溶 解度更大的 As(Ⅴ)进入溶液，同时 Sb(Ⅲ)氧化为 Sb(Ⅴ)，并形成难溶化合物 Sb2O3·2Sb2O5、Pb2Sb2O7 和 NaSb(OH)6， 进入浸出渣中；实验确定的最佳工艺条件为：NaOH 质量浓度 40 g/L，O2 分压 2.0 MPa，浸出温度 140 ℃，浸出 时间 2 h，液固质量比 10。在此条件下，As 的浸出率可达 95%以上，而 Sb 和 Pb 的浸出率均小于 1.0%。 关键词：高砷锑烟尘；氧压浸出；脱砷；苛性碱溶液 中图分类号：TF09；TF803.23 文献标志码：A 文章编号：1672?7207(2014)05?1390?07 Oxygen pressure leaching of arsenic and antimony bearing flue dust in NaOH solution ZHANG Xu, LIU Zhihong, LI Yuhu, LIU Zhiyong, LI Qihou (School of Metallurgy and Environment, Central South University, Changsha 410083, China) Abstract: The oxygen pressure leaching of arsenic and antimony bearing flue dust in NaOH solution was investigated and the effects of NaOH concentrate, O2 pressure, temperature, time and mass ratio of liquid to solid were evaluated experimentally. The results show that the main phases of arsenic and antimony in the flue dust produced in the pyrometallurgical treatment of anode slime of lead electrorefining are As2O3 and Sb2O3 separately, with a small amount of antimony also being in the form of Sb2O5. In the process of the oxygen pressure leaching of arsenic and antimony bearing flue dust in NaOH solution, As(Ⅲ) ions are oxidized into As(Ⅴ) with a higher dissolubility in alkaline solution in the leaching process, while Sb(Ⅲ) ions are also oxidized into Sb(Ⅴ) and precipitated into leach residue in the form of Sb2O3·2Sb2O5, Pb2Sb2O7 and NaSb(OH)6. The optimum condition of the leaching is determined to be as follows: NaOH concentrate of 40 g/L, O2 partial pressure of 2.0 MPa, temperature of 140 ℃, leaching time of 2 h, the mass ratio of liquid to solid of 10. Under the optimum conditions, the leaching rate of arsenic is more than 95%, while both of the leaching rates of anti