高分子物理浙江大学Introduction-2.pptVIP

Polymer Physics 高分子物理 徐君庭，沈烈 Teachers 任课教师 徐君庭 高分子大楼419;xujt@ 沈烈 高分子大楼310; shenlie@ Books and references教材与参考书 方征平，宋义虎，沈烈 高分子物理 (Polymer Physics) 浙江大学出版社, 杭州, 2008 何曼君，陈维孝，董西侠 高分子物理(修订版) 复旦大学出版社，上海，1990 金日光，华幼卿 高分子物理(第二版) 化学工业出版社，北京，2000 L. H. Sperling Introduction to Physical Polymer Science P. J. Flory Pricinples of Polymer Chemistry 网络课件地址： /polymerphysics/ 或 :8080/ka/index.htm 省级精品课程(2009年) Introduction 绪 论 Polymers are long-chain molecules of very high molecular weight, often measured in the hundreds of thousands 高分子是由成千上万个结构单元以共价键重复连接而成的长链分子 Polymer, or Macromolecule large molecule consisting of repeating smaller units (called monomer). e.g. (poly=many; mer=unit) Polymer 聚合物 Macromolecule 大分子 High Polymer 高聚物 Classification of synthetic polymers Physical Structure Linear polymers may be represented by a chain with two ends. Branched polymers have side chains, or branches, of significant length which are bonded to the main chain at branch points, and are characterized in terms of the number and size of the branches.Polymers with well-controlled modes of branching: comblike polymers, star polymers, dendrimers, etc. Network polymers have three-dimensional structures in which each chain is connected to all others, and are characterized by their crosslinking density or degree of crosslinking (number of junction points per unit volume). Plastics 塑料 Rubber 橡胶 Fiber 纤维 Adhesive 胶粘剂 Paint 涂料 Leather 皮革 … Preparation Method 2 types of preparation methods: addition polymers condensation polymers differences: condensation produces a byproduct, e.g. water condensation polymers often have non-C atoms in backbone chains Addition polymers formed by adding many monomer units together through chemical bonds e.g. polyethylene n CH2=CH2 ? -[CH2- CH2]-n ethylene monomer Polyethylene Other addition polymers: polypropylene, poly(methyl methacrylate), polystyrene, poly(vinyl chloride) Conden