无机分析技术在环境分析中的应用.ppt

ICP-OES和ICP-MS ICP-OES ICP-MS ICP - Inductively Coupled Plasma high temperature ion source decomposes, atomizes and ionizes the sample MS - Mass Spectrometer featuring quadrupole mass analyzer mass range - 7 to 260 amu (Li to U...) separates all elements in rapid sequential scan ions measured using dual mode detector ppt to ppm levels isotopic information available ICP-MS has the detection limits of GFAA and the sample throughput of ICP-OES ICP-OES ICP-MS构造图 1. Nebulizer 2. Spray Chamber 3. Plasma 4. Off-axis Lens 6. ORS 7. Mass Filter 8. Detector 5. Isolation Valve 样品导入装置 To ICP Babington Nebulizer Sample solution Ar carrier gas Peltier cooling device Cooling water Al insulation cover Ar blend gas 离子化（等离子体炬） + 1. Drying 2. Decomposition 3. Atomization 4. Ionization ID 2.5mm, Flow 0.2~0.4ml/min M+ M+ M+ M+ M+ M+ M+ M+ M+ M+ M+ M+ M ? M+ M ? M- ION SOURCE MASS FILTER DETECTOR Electron Impact Ionization (EI) Atmospheric Pressure Chemical Ionization (APCI) Electrospray Ionization (ESI) Chemical Ionization (CI) Matrix Assisted Laser Desorption Ionization (MALDI) Time Of Flight (TOF) Ion Trap Quadrupole Time to Frequency (TOFs only) Electron Multiplier Produces ions that are separated according to mass and detected A Mass Spectrometer Atmospheric Pressure Photo Ionization (APPI) ICP-MS特点 Excellent detection limits low ppb - ppt for all elements Wide elemental coverage - from Li - U over 70 elements measurable High throughput all elements determined simultaneously 20 element run/3 replicates/washout in 3 minutes Wide dynamic range linear over 9 orders Powerful semiquantitative analysis no standards needed Isotopic analysis isotope ratios isotope dilution Routine technique many users run systems overnight Small size saves lab space mobile installations Overview of Inorganic Analysis Techniques Atomic Absorption Spectrometry Light having a wavelength characteristic of the analyte is passed through the sample. The amount of light absorbed is proportional to conc