微波辐射下P(BMA2-EHMSt)复合凹凸棒高吸油树脂地制备.docVIP

微波辐射下P(BMA/2-EHM/St)复合凹凸棒高吸油树脂的制备 来水利1*，关悦1，张昭1,2，袁恒超1，袁启明1 （1.教育部轻化工助剂化学与技术重点实验室,陕西科技大学,西安 710021；2.咸阳职业技术学院，咸阳 712000） 摘 要：以甲基丙烯酸丁酯(BMA)、甲基丙烯酸异辛酯(2-EHM)和苯乙烯(St)为原料，过氧化二苯甲酰(BPO)为引发剂，聚乙烯醇(PVA)为分散剂，二乙烯基苯(DVB)为交联剂，改性凹凸棒(OATP)为无机添加物，在微波辐射下合成了高吸油树脂。探讨了St、BPO和OATP质量分数以及微波功率、反应温度和反应时间等对树脂吸油倍率的影响，用响应面法对合成工艺进行了优化，采用IR、TGA、SEM等对产物进行了结构表征与性能测试。结果表明：当St含量为52.54%（以单体的总质量为基准，下同）、m(2-EHM):m(BMA)=1:1.5、w(BPO)=1.95％、DVB加入量为0.60％（以单体的总质量为基准，下同）、PVA加入量为3.00％（以单体的总质量为基准，下同）、w(OATP)=2.00％，聚合温度82℃、反应时间70min、微波功率为700W时，所制得的高吸油树脂吸油倍率最大，对四氯化碳、二氯甲烷、甲苯和二甲苯的吸油倍率分别达到37.24、30.50、19.64、16.81g/g；添加OATP后树脂的热分解温度提高了32℃。 关键词：微波聚合；凹凸棒；高吸油树脂；响应曲面优化法 Preparation of High Oil-absorption Resin of P(BMA/2-EHM/St) Composited Attapulgite under Microwave Irradiation Lai Shuili1 Guan Yue1 Zhangzhao2,1 Yuan Hengchao1 Yuan Qiming1 Key laboratory of Auxiliary Chemistry technology for Chemical Industry, Ministry of Education. Shaanxi university of Science technology, Xian Shaanxi,710021,China 2.Xiangyang Vocational Technical College, Xianyang 712000, Shaanxi,China) ABSTRACT：Using Butyl methacrylate(BMA), 2-ethylhexyl methacrylate(2-EHM) and styrene(St) as raw material, polyvinyl alcohol(PVA) as dispersant agent, benzoyl peroxide(BPO) as initiator, divinylbenzene(DVB) as crosslinking agent, modified attapulgite as inorganic additive to prepare high oil-absorption resin with microwave irradiation. The influences, including mass fraction of initiator，styrene, OATP and reaction temperature, microwave power, reaction time were studied. The structure and performance of oil-absorption resins were analyzed by FTIR, TGA and SEM. The result shows: when the content of St is 52.54%、m(2-EHM) : m(BMA)=1:1.5、w(BPO)=1.95％、the content of DVB is 0.6％、the content of PVA is 3％、w(OATP)=2.0％，at 82℃, reaction time is 70min, micro-wave power is 700W, it has the maximum oil absorbency to carbon tetrachloride, dichloromethane, toluene and xylene. That is 37.24, 30.50, 16.94 and 16.81g/g, respectively, the thermal decompositio