二氧化碳高效缓蚀剂的筛选及缓蚀性得能研究-材料工程专业毕业论文.docxVIP

度的升高而增大，静态条件下KY-5能够很好的满足L80．1碳钢在静 度的升高而增大，静态条件下KY-5能够很好的满足L80．1碳钢在静 态单相模拟地层水介质中的防腐蚀要求，微量的KY-5缓蚀剂即可将 腐蚀速率降至部颁标准以下；动态条件下相比于静态结果，同一浓度 下时缓蚀率出现下降，当浓度为300ppm时，虽然缓蚀效率仍维持在 90％以上，但腐蚀速率仍大于部颁标准，难以满足L80．1碳钢在高温 下的防腐蚀要求，需要进一步加大缓蚀剂的添加剂量。 三、 在高温高压模拟地层水单相介质中，静态条件下KY-5缓蚀剂在 L80．1表面的吸附符合朗格缪尔等温吸附方程，其吸附为自发的化学 吸附过程，吸附膜层的稳定性随着温度的升高而降低。 四、 油水混合多相流中，KY-5缓蚀剂的缓蚀率随着浓度的升高而增大， 随着原油含量的升高而降低。在油水混合多相流条件下缓蚀剂倾向于 在油水界面聚集并在油相中发生吸附，造成水相介质中缓蚀剂浓度的 下降，影响缓蚀剂的缓蚀效果。 五、 物性测试结果表明：KY-5缓蚀剂水溶性优秀，无明显乳化倾向， 与地层水、防冻剂、阻垢剂都有较好的配伍性，且对油井中封隔器内 使用的橡胶皮筒无明显破坏作用，但其低温流动性较差，粘度较大， 需要与防冻剂配合使用。 关键词：CO：缓蚀剂，极值浓度，阳极脱附，多相流，油水混合介质 VI 万方数据 Optimization Optimization and Mechanism Research on the Efficient Corrosion Inhibitors used in C02 Corrosion System ABSTRACT The PVT analysis of oil field fotmd that the salinity and concentration of C￡一in formation water is extremely high，C02 acidic gas were also found in the associated gas，all the result indicate that the poor reservoir layer corrosion environment could lead to serious C02 corrosion problem during the future oil field exploitation．Among many corrosion control method，the corrosion inhibitor is widely used in the oil and gas industry due to their remarkable effect and convenient operation which could be a proper way to control the C02 corrosion problem in Halfaya oil field． As for the serious C02 corrosion problem in oil field，the optimization and mechanism research on the emcient corrosion inhibitors were conducted by laboratory simulation，the corrosion environment of C02 containing reservoir layer were simulated．The static weight loss test and electrochemical method were adapted to preliminary screen and evaluate the inhibition performance of 1 3 of commercial corrosion inhibitor under atmospheric pressure；the autoclave were used to study the inhibition performance of VⅡ 万方数据 北京化工大学硕士学位论文optimum 北京化工大学硕士学位论文 optimum inhibitor in simulated formation water and oil／water mixed media under the condition of high temperature pressure in the static and dynamic state；finally the physica