ASBR反应器厌氧氨氧化脱氮Ⅰ工艺特性与控制策略-中国环境科学.PDFVIP

中国环境科学 2013,33(12) ：2176~2183 China Environmental Science ASBR 反应器厌氧氨氧化脱氮 Ⅰ:工艺特性与控制策略 于德爽,李伟刚,李 津* (青岛大学化学化工与环境学院,环境工程系, 山东 青岛 266071) 摘要：采用 ASBR 厌氧氨氧化(ANAMMOX)反应器,考察了反应器启动特性并提出了反应器优化启动策略,并且从基质控制和环境控制两 方面分析了 ANAMMOX 工艺过程控制策略.启动优越性表现为:17d 结束菌体自溶,出现了 ANAMMOX 现象;第 51d 由物料衡算知 AAOB 的产量超过反硝化菌;经 100 多 d 的培养,获得了砖红色小颗粒状污泥. 由基质控制分析可知,要实现稳定运行,需控制进水 NO2--N 浓度低于 240mg/L,否则会受到亚硝酸盐的抑制. 由环境控制分析可知,ΔpH 与进水流量 Q 的乘积(ΔpH.Q) 同氨氮去除负荷之间存在良好的线性关系, pH 值可以用作反应器运行状况的指示性参数.同时发现,稳定阶段周期内的 ORP 与 pH 值具有良好线性关系,ORP 可以表述氨氮去除速率 的变化趋势,根据 ORP 曲线的“转折点”得到了 ANAMMOX 反应脱氮延迟时间. 关键词：厌氧氨氧化；ASBR 反应器；调控策略；稳定性 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2013)12-2176-08 Nitrogen removal in the Anammox sequencing batch reactor Ⅰ: Performance and control strategies. YU De-shuang, * LI Wei-gang, LI Jin (Department of Environmental Engineering, College of Chemical Science and Engineering, Qingdao University, Qingdao 266071, China). China Environmental Science, 2013,33(12)：2176~2183 Abstract ：The start-up of ANAMMOX process using a sequencing batch reactor was investigated and the characteristics and control strategies during start-up were explored. Furthermore, process control strategies were also analyzed from two aspects of substrate control and environment control. ANAMMOX phenomenon was observed after 17days with the end of cell lysis phase. Thus, by the material balance, daily production of ANAMMOX bacteria was more than denitrifying bacteria. The granular red-brown ANAMMOX sludge was obtained after 100-day start-up. When the ANAMMOX reactor was successfully started-up, the analysis of the effects of substrates concentrations indicated that the ANAMMOX process was inhibited when the nitrite concentration was higher than 240mg/L. The analysis of the operation process indicated a good correlation between NH4+-N removal rate and the value of ΔpH·Q