高温氮化制备氮化物结合mgal2o4-c工复合材料及其性能.docxVIP

AbstractCarbon Abstract Carbon containing refractories have been widely used in steelmaking due to their excellent thermal shock and slag resistance．However,carbon containing refractories affect the production of clear steel due to its easier oxidation．High quality fused spinel，flake graphite and silicon powder were used as primary materials．In-situ nitriding tO form 3-Sialon and A10N to improve the strength and properties of MgAl204·C materials． (1)Nitriding temperature and nitriding time have a important effect on the 3-Sialon bonded MgAl204-C materials and AION bonded MgAl204一C materials．The samples were sintered at 1400℃，1450℃，1500℃，1550。C and 1600。C for lh，2h，3h and 4h respectively．The results show that p—Sialon was formed in the samples sintered at 1400。C，1450。C and 1500℃，the compressive strength(64．75MPa)and bending strength(15．18MPa)are generated when the temperature is 1450。C．AION was formed in else samples sintered at 1 550。C and 1600。C，the compressive strength (58．44MPa)and bending strength(14．27MPa)are generated when the temperature is 1550。C．Compared with traditional MgAl204-C materail，13-Sialon or A10N bonded MgAl204-C materails has better properties．Because of 3-Sialon，AION can form direct chemical bonding with MgAl204 and C．The optimal nitriding temperature of SMAC material is 1450。C．And，the optimal nitriding temperature of AMAC material is 1550℃． (2)The experiment of slag corrosion resistance for SMAC and AMAC materials were carried out with static crucible method．In the process of slag corrosion，3-Sialon， Si3N4 and SiC happened to oxide and dissolved into slag,which increase the ciscosity of slag and prevent the further slag penetration．Apparent activations energy are 202kJ／mol and 141kJ／mol respectively．And，the oxide of AION can produce A120(g) and N2(g)to prevent the further penetration．The alumina rich spinel can absorbed FeO from the slag to form a solid solution and the reaction of A1203 and CaO produced A1203一CaO compounds with high melting p