快速凝固稀土AZ31的显微组织及耐蚀性研究.docVIP

PAGE 快速凝固稀土AZ31的显微组织及耐蚀性研究 摘 要 镁合金是目前工程应用中最轻的工程结构材料，具有比强度高、比模量高、易于切削加工、电磁屏蔽性能优异、可以回收利用以及资源丰富等特点，在汽车、摩托车、航空航天、飞行器、医用材料、电子产品等领域具有广阔的应用前景。但是镁合金在空气中极易氧化，与水很容易反应，其电极电位是所有工程结构材料中最低的，因此其耐腐蚀性能很差，严重地制约了镁合金的发展和应用。 本课题利用单辊快速凝固技术制备了不同甩带速度下的稀土AZ31镁合金薄带。并利用光学显微分析、XRD分析、SEM分析和电化学分析等测试手段，研究了快速凝固稀土镁合金AZ31的显微组织（第二相的数量、形态和分布等）对镁合金耐腐蚀性能的影响。 研究表明，快速凝固稀土AZ31主要由α-Mg相和β-Mg17Al12相组成；随着冷却速度的增大，α相晶粒愈加细小，第二相β相对量增加并且分布更加弥散。电化学分析表明，随着冷却速度的提高，快速凝固稀土AZ31镁合金的耐腐蚀性能明显增强。 关键词：稀土AZ31，快速凝固，显微组织，耐腐性 The Study on Microstructure and Corrosion Resistance of Rapidly Solidified Rare-Earth AZ31 Abstract Magnesium alloys are the lightest of the engineering project application of engineering structure material, has more than high strength, high modulus, easy than cutting processing, electromagnetic shielding the outstanding performance, can be recycled and rich in resources and other characteristics, in the automobile, motorcycle, aerospace, aircraft, medical materials, electronic products and other areas it has wide application prospects. But magnesium alloys in the air is easy to oxidation, and the water is very easy to reaction, the electrode potential of magnesium alloy is the lowest of all engineering structure material, so its corrosion resistance is poor, and seriously restricted the development and application of magnesium alloy. The subject uses single-roll rapid solidification to prepare the rare earth AZ31 magnesium alloy strip with the different speeds . And the use of metallographic analysis, XRD analysis, SEM analysis and electrochemical analysis test tools, analysis of the rapidly solidified magnesium alloy AZ31 microstructure morphology and microstructure of rapidly solidified magnesium alloy (the second phase of the count, morphology and distribution, etc.) on the corrosion resistance of magnesium alloy effect The study found that rare-earth rapidly solidified AZ31 mainly by the α and β-Mg17Al12 phase composition. by XRD and SEM analysis found that with increasing cooling rate, α-phase grai